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ZGH451镍基高温合金SLM成形开裂机理分析
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1.宁波大学 材料科学与化学工程学院;2.中国科学院宁波材料技术与工程研究所;3.中国科学院金属研究所 师昌绪先进材料创新中心;4.宁波中科祥龙轻量化科技有限公司

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中国科学院国际伙伴计划;浙江省“领雁”项目;“3315计划”C类创新团队;甬江人才工程科技创新领域青年项目;浙江省“尖兵”研发攻关计划;宁波市重大科技任务攻关项目


Analysis of the SLM forming structure and cracking mechanism of ZGH451 nickel-based high-temperature alloy
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中国科学院国际伙伴计划(181GJHZ2023132MI);浙江省“领雁”项目(2024C01121);“3315计划”C类创新团队(2020A-27-C);甬江人才工程科技创新领域青年项目(2021A-112-G,2022A-202-G);浙江省“尖兵”研发攻关计划(2023C01053); 宁波市重大科技任务攻关项目(2022Z190)

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    摘要:

    本文以SLM成形ZGH451镍基高温合金为研究对象,揭示凝固液膜导致裂纹萌生的机理,澄清合金元素、织构对裂纹缺陷产生的作用。实验结果表明:ZGH451镍基高温合金SLM成形过程中产生的裂纹主要分为内部凝固裂纹和边缘冷裂纹两类。在凝固末期枝晶间存在低熔点相液膜,凝固前沿高熔点Cr元素颗粒会阻碍熔体补缩,枝晶间液膜在补缩不足和枝晶热应力的双重作用下发生破裂导致材料心部凝固裂纹的形成。合金轮廓区域冷却速率高、热应力大,累积的残余应力超过材料强度极限或晶界结合强度导致冷裂纹形成。输入激光能量密度低于53.6J/mm3时合金中气孔与未熔合大量产生,超过130.9 J/mm3时沿熔池轨迹锁孔形成概率陡增,这些缺陷会在应力作用下诱发裂纹。枝晶间析出的TiC等颗粒越多、晶粒取向差越大合金裂纹敏感性越高。沉积态ZGH451镍基高温合金以γ、γ′相为主,样品在(100)晶面具有择优取向,晶粒平均纵横比达到11.25,组织织构显著加剧了晶粒边缘与尖端应力集中,促进裂纹的萌生、改变裂纹延伸方向。

    Abstract:

    This study focuses on the SLM (Selective Laser Melting) formed ZGH451 nickel-based superalloy, revealing the mechanism by which solidification liquid films lead to crack initiation and clarifying the roles of alloy elements and texture in forming crack defects. Experimental results indicate that cracks in the SLM process of ZGH451 nickel-based superalloy can be mainly categorized into internal solidification cracks and edge cold cracks. During the late solidification stage, low-melting-point phase liquid films exist between dendrites, and high-melting-point Cr element particles at the solidification front hinder melt feeding. The insufficient feeding and thermal stress between dendrites cause the liquid film"s rupture, leading to solidification cracks in the core of the material. In the alloy"s contour region, high cooling rates and significant thermal stress lead to residual stress accumulation, which exceeds the material"s strength limit or grain boundary cohesion strength, resulting in the formation of cold cracks. When the input laser energy density is below 53.6 J/mm3, pores and lack of fusion defects increase significantly in the alloy, while exceeding 130.9 J/mm3 sharply increases the probability of keyhole formation along the melt pool track. These defects can induce cracks under stress. The more TiC and other carbide particles precipitate between dendrites, the greater grain misorientation, and the higher the alloy"s crack sensitivity. The deposited state of ZGH451 nickel-based superalloy is mainly composed of γ and γ" phases, with a preferred orientation on the (100) plane. The average aspect ratio of the grains reaches 11.25, and the significant texture exacerbates stress concentration at the grain edges and tips, promoting crack initiation and altering crack propagation direction.

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吴寅,张浩,朱玉平,方世民,丁尧瑶,梁力文,闫光强,邱子翔,王海轩,东野生栓,田苗诚,杨阳,黄其忠,郑永健. ZGH451镍基高温合金SLM成形开裂机理分析[J].稀有金属材料与工程,,().[wuyin, Zhang Hao, Zhu Yuping, Fang Shimin, Ding Yaoyao, Liang Liwen, Yan Guangqiang, Qiu Zixiang, Wang Haixuan, Dongye Shengshua, Tian Miaocheng, Yang Yang, Huang Qizhong, Zheng Yongjian. Analysis of the SLM forming structure and cracking mechanism of ZGH451 nickel-based high-temperature alloy[J]. Rare Metal Materials and Engineering,,().]
DOI:10.12442/j. issn.1002-185X.20240487

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  • 收稿日期:2024-08-04
  • 最后修改日期:2024-09-06
  • 录用日期:2024-09-12
  • 在线发布日期: 2024-11-21
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