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稀有金属对钢海洋大气腐蚀行为影响的研究进展
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作者单位:

1.国防科技大学 空天科学学院,湖南 长沙 410073;2.中国人民解放军91980部队,山东 烟台 264000

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中图分类号:

TG172.3

基金项目:

动态极端环境材料技术重点实验室项目(2023SCKT1102);湖南省自然科学基金面上项目(2024JJ5406)


Research Progress on Effects of Rare Metals on Marine Atmospheric Corrosion Behavior of Steel
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Affiliation:

1.College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China;2.The No.91980 Troop of PLA, Yantai 264000, China

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    摘要:

    钢作为海洋工程装备的结构材料在海洋大气环境中会受海盐气溶胶、氯离子等因素的影响而发生严重的海洋大气腐蚀。向钢中添加稀有金属能够调控钢的组织、促进锈层致密化从而改善耐海洋大气腐蚀性能。本文综述了近年来世界各地学者关于稀有金属添加对钢耐海洋大气腐蚀性能影响的相关研究,总结了碳钢、不锈钢、耐候钢等典型海洋工程用结构钢在海洋大气环境中腐蚀的原因,归纳了添加Nb、Mo、Sb、Sn、Ce、La、Y等稀有金属影响钢的组织和腐蚀过程中锈层结构的作用机制。对于耐候钢和碳钢,主要讨论了稀有金属元素对锈层结构产生的影响;针对不锈钢,主要讨论了稀有金属元素对夹杂物改性及对不锈钢点蚀行为的作用机制。对未来的相关研究方向进行了展望,以期对结构钢耐海洋大气腐蚀性能的提升及其在海洋工程中的应用提供参考。

    Abstract:

    Steel material is the main structural material of marine equipment, but its corrosion usually occurs in the marine atmosphere environment, thus affecting its service performance. Compared with general atmospheric corrosion, marine atmospheric corrosion is affected by sea salt aerosols, chloride ions and other specific factors of marine atmosphere. In addition, the marine atmospheric corrosion properties of steel materials are closely related to the alloying elements of the materials. This paper reviewed the relevant studies of worldwide scholars on the effect of rare metal doping on the marine atmospheric corrosion resistance of steel materials in recent years, and summarized the corrosion mechanism of carbon steel, stainless steel, weathering steel and other common structural steels under marine atmospheric environment. The effects of Nb, Mo, Sb, Sn, Ce, La, Y and other rare metal elements on the marine atmospheric corrosion resistance of steel materials were analyzed. For weathering steel and carbon steel, the effect of rare metal elements on the structure of rust layer was mainly discussed. For stainless steel, the effect mechanism of rare metal elements on inclusion modification and pitting behavior of stainless steel was discussed. The future research directions were prospected, in order to provide references for the application of rare metal doped steel in marine atmospheric environment and for the improvement of marine atmospheric corrosion resistance.

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刘飞洋,李田科,王睿鑫,郭斌,艾园林,唐宇.稀有金属对钢海洋大气腐蚀行为影响的研究进展[J].稀有金属材料与工程,2025,54(3):791~802.[Liu Feiyang, Li Tianke, Wang Ruixin, Guo Bin, Ai Yuanlin, Tang Yu. Research Progress on Effects of Rare Metals on Marine Atmospheric Corrosion Behavior of Steel[J]. Rare Metal Materials and Engineering,2025,54(3):791~802.]
DOI:10.12442/j. issn.1002-185X.20240533

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历史
  • 收稿日期:2024-08-17
  • 最后修改日期:2024-11-14
  • 录用日期:2024-11-18
  • 在线发布日期: 2025-03-25
  • 出版日期: 2025-03-25