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纳米ZrC增强WNiFe合金的微观结构及性能研究
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1.中国科学技术大学;2.中国科学院固体物理研究所

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基金项目:

国家重点研发计划(2022YFE03140002, 2019YFE03110200),国家自然科学基金项目(面上项目52273320, 52173303, 52171084),国家杰出青年科学基金 (52325103)


Microstructure and properties of ZrC nanoparticles strengthened WNiFe alloys
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1.University of Science and Technology of China;2.Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences

Fund Project:

National Key Research and Development Program of China (Grant Nos. 2022YFE03140002, 2019YFE03110200), National Natural Science Foundation of China (Grant Nos. 52273320, 52173303, 52325103, 52171084)

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    摘要:

    钨是聚变堆面向等离子部件及散裂中子源靶体的候选材料,但其室温脆性和辐照脆性极大地限制其应用。高比重钨合金由于具有室温延展性和低成本的优点,被认为是一种良好的替代材料。在本研究中,通过放电等离子烧结和旋锻制备了纳米ZrC颗粒强化的93W-4.9Ni-2.1Fe合金。结果表明,少量纳米ZrC颗粒的添加可以细化晶粒并提高WNiFe合金的硬度,但会阻碍烧结过程中γ-(Ni,Fe)相的形成。因此,放电等离子体烧结的WNiFe和WNiFe-ZrC合金在室温下是脆性的。而采用无压液相烧结和旋锻制备的WNiFe及WNiFe-0.5wt%ZrC合金具有室温塑性。在400 °C时,旋锻WNiFe-0.5 wt%ZrC的抗拉强度和延伸率均高于WNiFe合金。纳米颗粒在W晶粒和γ-(Ni,Fe)相中分布,能够钉扎位错和晶界,显著提高合金强度。旋锻WNiFe-0.5 wt%ZrC的室温热导率仅为71 Wm-1K-1,但在800 °C时增加到约100 Wm-1K-1,与纯W (121 Wm-1K-1)的热导率相近,具有用作聚变堆面向等离子体材料的潜力。

    Abstract:

    Tungsten (W) is one of the most promising plasma-facing materials in nuclear fusion devices and candidate target materials for spallation neutron source, however its applications are greatly hindered by its room-temperature brittleness and irradiation-induced embrittlement. W heavy alloys with room temperature ductility and low cost were considered as alternative materials. In this work, 93W-4.9Ni-2.1Fe alloys strengthened by nanoscale ZrC particles were fabricated by spark-plasma-sintering (SPS) and hot rotary swaging, respectively. The addition of a small amount of ZrC nanoparticles can refine grain size and increase the hardness of the WNiFe alloys, but hinder the formation of the γ-(Ni, Fe) phase during SPS. The SPS WNiFe and WNiFe-ZrC alloys are brittle at room temperature, while the swaged WNiFe and WNiFe-0.5 wt% ZrC alloys are ductile at room temperature. At 400 °C, the swaged WNiFe-0.5 wt% ZrC alloy exhibits both higher tensile strength and better ductility than the swaged WNiFe. The nanoscale particles distributed in the W grains and γ-(Ni,Fe) phase provided a good pinning effect and enhanced the strength. The thermal conductivity of swaged WNiFe-0.5 wt%ZrC is 71 Wm-1K-1 at room temperature, but it increases to about 100 Wm-1K-1 at 800 °C, which is close to that of pure W (121 Wm-1K-1). These results show the potential of WNiFe alloys as candidate materials for fusion applications.

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杨润,王慧,刘瑞,吴学邦,王先平,方前锋,刘长松.纳米ZrC增强WNiFe合金的微观结构及性能研究[J].稀有金属材料与工程,,().[Yang Run, Wang Hui, Liu Rui, Wu Xuebang, Wang Xianping, Fang Qianfeng, Liu Changsong. Microstructure and properties of ZrC nanoparticles strengthened WNiFe alloys[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-09-30
  • 最后修改日期:2025-01-13
  • 录用日期:2025-01-21
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