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纳米ZrC增强WNiFe合金的微观结构及性能
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1.中国科学技术大学,安徽 合肥 230026;2.中国科学院 合肥物质科学研究院 固体物理研究所,安徽 合肥 230031

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基金项目:

国家重点研发计划(2022YFE03140002, 2019YFE03110200),国家自然科学基金项目(面上项目52273320, 52173303, 52171084),国家杰出青年科学基金 (52325103)


Microstructure and Properties of ZrC Nanoparticles- Strengthened WNiFe Alloys
Author:
Affiliation:

1.University of Science and Technology of China, Hefei 230026, China;2.Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

Fund Project:

National Key Research and Development Program of China (2022YFE03140002, 2019YFE03110200); National Natural Science Foundation of China (52273320, 52173303, 52325103, 52171084); Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0470000); Anhui Provincial Natural Science Foundation (2308085J07); HFIPS Director's Fund (YZJJ202102, YZJJQY202306, YZJJKX202202)

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    摘要:

    分别通过放电等离子烧结和旋锻制备了纳米ZrC颗粒强化的93W-4.9Ni-2.1Fe合金。结果表明,少量纳米ZrC颗粒的添加可以细化晶粒并提高WNiFe合金的硬度,但会阻碍烧结过程中γ-(Ni,Fe)相的形成。因此,放电等离子体烧结的WNiFe和WNiFe-ZrC合金在室温下是脆性的。而采用无压液相烧结和旋锻制备的WNiFe及WNiFe-0.5ZrC(wt%)合金具有室温塑性。在400 ℃时,旋锻WNiFe-0.5ZrC的抗拉伸强度和延伸率均高于WNiFe合金。纳米颗粒在W晶粒和γ-(Ni,Fe)相中分布,能够钉扎位错和晶界,显著提高合金强度。旋锻WNiFe-0.5ZrC的室温热导率仅为71 W·m-1·K-1,但在800 ℃时增加到约100 W·m-1·K-1,与纯W的热导率(121 W·m-1·K-1)相近,具有用于聚变堆的面向等离子体材料的潜力。

    Abstract:

    93W-4.9Ni-2.1Fe alloys strengthened by nanoscale ZrC particles were prepared by spark-plasma-sintering (SPS) and hot rotary swaging, separately. Results show that the addition of a small number of ZrC nanoparticles can refine grains and increase the hardness of the WNiFe alloys, but hinder the formation of the γ-(Ni, Fe) phase during SPS. SPSed WNiFe and WNiFe-ZrC alloys are brittle at room temperature, while the swaged WNiFe and WNiFe-0.5ZrC (wt%) alloys are ductile. At 400 °C, the swaged WNiFe-0.5ZrC alloy exhibits both higher tensile strength and better ductility than the swaged WNiFe. The nanoscale particles distributed in the W grains and γ-(Ni, Fe) phase provide a good pinning effect, which enhances the strength. The thermal conductivity of swaged WNiFe-0.5ZrC is only 71 W·m-1·K-1 at room temperature, but it increases to about 100 W·m-1·K-1 at 800 °C, which is close to that of pure W (121 W·m-1·K-1). These results show the potential of WNiFe alloys as plasma-facing materials in fusion reactor.

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杨润,王慧,刘瑞,吴学邦,王先平,方前锋,刘长松.纳米ZrC增强WNiFe合金的微观结构及性能[J].稀有金属材料与工程,2025,54(7):1661~1670.[Yang Run, Wang Hui, Liu Rui, Wu Xuebang, Wang Xianping, Fang Qianfeng, Liu Changsong. Microstructure and Properties of ZrC Nanoparticles- Strengthened WNiFe Alloys[J]. Rare Metal Materials and Engineering,2025,54(7):1661~1670.]
DOI:10.12442/j. issn.1002-185X.20240635

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历史
  • 收稿日期:2024-09-30
  • 最后修改日期:2025-01-13
  • 录用日期:2025-01-21
  • 在线发布日期: 2025-07-01
  • 出版日期: 2025-06-23