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氮气流量对质子交换膜电解槽双极板上TaN涂层微观结构与耐腐蚀性能的影响
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1.西安交通大学 金属材料强度国家重点实验室,陕西 西安 710049;2.西部金属材料股份有限公司,陕西 西安 710201

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基金项目:

国家自然科学基金项目(面上项目,重点项目,重大项目)


Influence of N2 Flow Rate on Microstructure and Corrosion Resistance of TaN Coatings on Bipolar Plates of PEM Electrolyser
Author:
Affiliation:

1.State Key Laboratory for Mechanical Behavior of Materials, Xi 'an Jiaotong University, Xi 'an 710049, China;2.Western Metal Materials Co., Ltd, Xi 'an 710201, China

Fund Project:

National Key Research and Development Program of China (2022YFB4002100); National Natural Science Foundation of China (52271136); Natural Science Foundation of Shaanxi Province (2021JC-06)

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    摘要:

    通过磁控溅射在钛基双极板上沉积了TaN涂层,以提高其耐腐蚀性和使用寿命,并研究了氮气流量对TaN涂层的表面形貌、疏水性、结晶度、耐腐蚀性能和界面接触电阻的影响。结果表明:随着氮气流量的增加,TaN涂层的粗糙度先减小后增大,疏水性先增大后减小。在氮气流量为3 mL/min时,TaN涂层晶粒较大,呈现出较低的粗糙度和较高的疏水性。在模拟的质子交换膜电解槽环境中,该涂层具有最低的腐蚀电流密度(2.82 μA·cm-2)和最高的自腐蚀电位(-0.184 V vs. SCE)。经过10 h恒电位极化测试后,在氮气流量为3 mL/min时沉积的TaN涂层上观察到的腐蚀坑较少。经过75 h的电解水性能测试,TaN涂层提高了钛双极板腐蚀电阻,进而提高了电解池的电解效率(68.87%),大幅度降低双极板成本。

    Abstract:

    TaN coatings were deposited on Ti bipolar plates by magnetron sputtering to improve corrosion resistance and service life. The influence of N2 flow rate on the surface morphology, hydrophobicity, crystallinity, corrosion resistance, and interfacial contact resistance of TaN coatings was studied. Results show that as the N2 flow rate increases, the roughness of TaN coatings decreases firstly and then increases, and the hydrophobicity increases firstly and then decreases. At the N2 flow rate of 3 mL/min, TaN coating with larger grain size presents lower roughness and high hydrophobicity. The coating possesses the lowest corrosion current density of 2.82 μA·cm-2 and the highest corrosion potential of -0.184 V vs. SCE in the simulated proton exchange membrane water electrolyser environment. After a potentiostatic polarization test for 10 h, a few corrosion pits are observed on the TaN coatings deposited at an N2 flow rate of 3 mL/min. After 75 h of electrolytic water performance testing, the TaN coating on bipolar plate improves the corrosion resistance and thus enhances the electrolysis efficiency (68.87%), greatly reducing the cost of bipolar plates.

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高建平,吕源江,李永婧,孙雯倩,任碧莹,戴正飞,马飞.氮气流量对质子交换膜电解槽双极板上TaN涂层微观结构与耐腐蚀性能的影响[J].稀有金属材料与工程,2025,54(5):1127~1133.[Gao Jianping, Lv Yuanjiang, Li Yongjing, Sun Wenqian, Ren Biying, Dai Zhengfei, Ma Fei. Influence of N2 Flow Rate on Microstructure and Corrosion Resistance of TaN Coatings on Bipolar Plates of PEM Electrolyser[J]. Rare Metal Materials and Engineering,2025,54(5):1127~1133.]
DOI:10.12442/j. issn.1002-185X.20240720

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  • 收稿日期:2024-11-04
  • 最后修改日期:2024-12-05
  • 录用日期:2025-01-03
  • 在线发布日期: 2025-05-23
  • 出版日期: 2025-05-22