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钎焊材料成分设计准则及典型组织演变机制
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中国机械总院集团郑州机械研究所有限公司 高性能新型焊接材料全国重点实验室,河南 郑州 450052

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the National Natural Science Foundation of China (U22A20191)


Design Guidelines for Composition of Brazing Filler Metals and Evolution Mechanisms of Typical Microstructures
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State Key Laboratory of High Performance & Advanced Welding Materials, China Academy of Machinery Zhengzhou Research Institute of Mechanical Engineering Co., Ltd, Zhengzhou 450052, China

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National Natural Science Foundation of China (U22A20191)

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    摘要:

    钎焊材料应用广泛,在异质结构连接中发挥着工业万能胶的作用。新结构和新材料层出不穷,所需要的新型钎焊材料越来越多。研究钎料成分优化设计方法,形成钎料系统性设计准则意义重大。从应用钎料基本性能、成形加工性和综合成本三维视角出发,阐明了钎料成分设计的基本规则。本研究中钎料本构性能包括钎料机械性能、物理化学性能、电磁性能、耐蚀性能与钎焊作业时钎料的润湿性和流铺性。成型加工性包括熔炼、铸造工艺,挤压、轧制、拉拔、制环工艺,制粒、制粉和非晶微晶成型工艺。成本指材料价值和制造成本之和。提高钎料综合性能需要全面系统考量设计指标,突出钎料特色要聚焦相应技术指标,二元或三元共晶组织可以有效提高钎料流铺性,固溶体组织有利于钎料成形。采用所提出的设计准则,设计了典型的Ag基、Cu基、Zn基、Sn基钎料,并在重大科学工程中得到成功应用。

    Abstract:

    Brazing filler metals are widely applied, which serve as an industrial adhesive in the joining of dissimilar structures. With the continuous emergence of new structures and materials, the demand for novel brazing filler metals is ever-increasing. It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals. This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals, formability and processability, and overall cost. The basic properties of brazing filler metals refer to their mechanical properties, physicochemical properties, electromagnetic properties, corrosion resistance, and the wettability and fluidity during brazing. The formability and processability of brazing filler metals include the processes of smelting and casting, extrusion, rolling, drawing and ring-making, as well as the processes of granulation, powder production, and the molding of amorphous and microcrystalline structures. The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost. Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators. Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators. Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals, and solid solution structures contribute to the formability. By employing the proposed design guidelines, typical Ag based, Cu based, Zn based brazing filler metals, and Sn based solders were designed and successfully applied in major scientific and engineering projects.

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龙伟民.钎焊材料成分设计准则及典型组织演变机制[J].稀有金属材料与工程,2025,54(4):837~853.[Long Weimin. Design Guidelines for Composition of Brazing Filler Metals and Evolution Mechanisms of Typical Microstructures[J]. Rare Metal Materials and Engineering,2025,54(4):837~853.]
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  • 收稿日期:2025-03-01
  • 最后修改日期:2025-03-28
  • 录用日期:2025-03-28
  • 在线发布日期: 2025-04-23
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