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ttao相结构对ZrO2陶瓷透光度的影响
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清华大学材料学院,清华大学材料学院,清华大学材料学院,清华大学材料学院,清华大学材料学院

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清华大学教改项目(项目号ZY01_02);清华大学SRT项目(项目号1612T0027)


Influence of phase structure on the transmittance of ZrO2 ceramics
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School of Materials Science and Engineering,Tsinghua University,School of Materials Science and Engineering,Tsinghua University,School of Materials Science and Engineering,Tsinghua University,School of Materials Science and Engineering,Tsinghua University,School of Materials Science and Engineering,Tsinghua University

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    摘要:

    研究了相结构对ZrO2陶瓷透光度的影响。本文制备了3 mol%Y2O3稳定ZrO2(3YSZ)和5 mol%Y2O3稳定ZrO2(5YSZ),分别在1450℃、1500℃、1550℃下烧结,通过XRD、SEM、EMPA等研究了3YSZ和5YSZ相结构和相含量,用UV-Vis分光光度计测试其在可见光范围内的透光率,探讨相结构和透光度的关系。结果表明,3YSZ和5YSZ均为稳定四方相 (t相)和亚稳定四方相 (t′相)的两相复合物,其中3YSZ以t相为主,且t相含量随烧结温度的升高而增加,透光性较差;5YSZ以t′为主,且t′相含量随烧结温度的升高而增加,透光性较好。得出结论,t相透光性较差,t′相透光性较好,并对此进行解释。

    Abstract:

    The phase structure plays an important role on the transmittance of zirconia ceramics. In this paper, 3 mol% Y2O3-stabilized ZrO2 (3YSZ) and 5 mol% Y2O3-stablized ZrO2 (5YSZ) were prepared, and sintered at 1450℃, 1500℃ and 1550℃ respectively. The phase structure and constitution of the specimens were characterized by XRD, SEM and EMPA. And the transmittance of the specimens was tested by UV-Vis spectrophotometer in the visible range. The relationship between the phase structure and the transmittance is discussed. The results reveal that 3YSZ and 5YSZ both have a binary assemblage of t and t′ phases, while more t phase was found in the 3YSZ, and more t′ phase was found in 5YSZ, the content of which increase with the sintering temperature seperately. The transmittance of 5YSZ is higher than that of 3YSZ in the visible light range. Concerning the phase structures and the transmittance of 3YSZ and 5YSZ, the conclusion that the transmittance of t′ phase is higher than that of t phase is brought forth.

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赵晓慧,吴音,尹笑然,樊婷婷,林青昱. ttao相结构对ZrO2陶瓷透光度的影响[J].稀有金属材料与工程,2018,47(S1):18~21.[Zhao Xiaohui, Wu Yin, Yin Xiaoran, Fan Tingting, Lin Qingyu. Influence of phase structure on the transmittance of ZrO2 ceramics[J]. Rare Metal Materials and Engineering,2018,47(S1):18~21.]
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  • 收稿日期:2017-05-20
  • 最后修改日期:2017-05-20
  • 录用日期:2018-01-29
  • 在线发布日期: 2018-10-22
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