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利用SiO2聚空心微球调控多孔Si2N2O陶瓷微观形貌
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清华大学材料学院,清华大学材料学院,,中北大学材料科学与工程学院,清华大学材料学院,清华大学材料学院,清华大学材料学院

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国家自然科学基金资助(项目号51572140)


Pore Morphology Design of Porous Si2N2O Ceramics via Silica Poly-Hollow Microspheres
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State Key Lab of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,State Key Lab of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,,School of Materials Science and Engineering,North University of China,State Key Lab of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,State Key Lab of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,State Key Lab of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University

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    摘要:

    本文以氧化硅聚空心微球作为造孔剂,将其添加到氮化硅浆料中,利用高温下氮化硅与氧化硅之间的液相烧结反应生成氮氧化硅相,同时氧化硅聚空心微球中的空隙作为气孔来源以得到多孔氮氧化硅陶瓷。文章通过调节浆料固相含量对多孔陶瓷的微观形貌及力学性能进行调控。结果表明:氮化硅浆料固相含量的增加使得多孔陶瓷的氮氧化硅相含量增加,孔形貌发生了显著改变,开孔气孔率由65.4%降低至51.7%,抗弯强度则由10.55 MPa增加到26.74 MPa。

    Abstract:

    In this research, as pore-forming agents, silica poly-hollow microspheres were added into Si3N4 slurries, and Si2N2O phase was generated by the liquid phase sintering reaction between SiO2 and Si3N4. Moreover, the space occupied by the silica poly-hollow microspheres would become the pores after the sintering process, and porous Si2N2O ceramics were fabricated. The morphology and mechanical properties of porous Si2N2O ceramics could be well regulated by adjusting the solid loading of Si3N4 slurry. The results show that with the increase of Si3N4 slurry solid loading, the content of Si2N2O phase increases and their porous structure has great changes. Besides, their open porosity decreases to 51.7% and their flexural strength increases to 26.74 MPa.

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张笑妍,霍文龙,兰天,崔杰,干科,闫姝,杨金龙.利用SiO2聚空心微球调控多孔Si2N2O陶瓷微观形貌[J].稀有金属材料与工程,2018,47(S1):41~44.[Xiaoyan Zhang, Wenlong Huo, Tian Lan, Jie Cui, Ke Gan, Shu Yan, Jinlong Yang. Pore Morphology Design of Porous Si2N2O Ceramics via Silica Poly-Hollow Microspheres[J]. Rare Metal Materials and Engineering,2018,47(S1):41~44.]
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  • 收稿日期:2017-05-23
  • 最后修改日期:2017-05-23
  • 录用日期:2018-01-29
  • 在线发布日期: 2018-10-22
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