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发泡剂浓度对钙长石多孔陶瓷结构与性能的影响
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北京交通大学机械与电子控制工程学院,北京交通大学机械与电子控制工程学院,北京交通大学机械与电子控制工程学院,清华大学材料学院

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国家自然科学基金资助(项目号51472023)


Effects of foaming agent Content on the Structure and Properties of PorousAnorthite Ceramics
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Beijing Jiaotong University,School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University,,

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    摘要:

    本文以a-Al2O3、SiO2和CaCO3为主要原料,采用泡沫注凝法+无压烧结原位合成制备钙长石多孔陶瓷,通过调控发泡过程中发泡剂浓度以获得不同气孔结构的多孔陶瓷样品。采用XRD分析了制备材料的物相组成,采用SEM观察了制备材料的显微结构,并测试了制备材料的气孔率、体积密度、抗压强度等性能。综合测试结果与分析结果,探究了发泡剂浓度对制备材料的显微结构与性能的影响规律。研究结果表明:在同等烧结温度下,发泡剂浓度对制备材料的物相组成影响不大,发泡剂浓度对气孔率、孔径分布、抗压强度及热导率均有显著影响:随着发泡剂浓度的增大气孔率先增加最后缓慢下降,抗压强度先下降最后缓慢增加。在发泡剂浓度为0.5~32 g/L的范围内,制备材料的气孔率为82.14~90.61%,抗压强度为0.14~3.84 MPa。

    Abstract:

    Porous anorthite ceramics were fabricated by foam-gelcasting and pressureless sintering method, using α-Al2O3,SiO2 and CaCO3 as raw materials . By adjusting the foaming agent concentration during foaming process, pore structure could be tailored. XRD was used to analyze phase composition of prepared materials. The microstructure of prepared materials was observed by SEM. Some porperties such as the porosity, bulk density, compressive strength were tested. The influences of foaming agent concentration on the microstructure and properties of materials were studied. The results show that concentration of foaming agent has little effects on the phase composition. While the porosity and pore structure are significantly effected by foaming agent concentration. The compressive strength is obviously influenced too. Through adjusting foaming agent concentration in the range of 0.5 ~ 32 g/L, single phase porous anorthite ceramics with compressive strength of 0.14~3.84 MPa, porosity of 82.14~90.61 % could be fabricated.

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武令豪,李翠伟,田雪,汪长安.发泡剂浓度对钙长石多孔陶瓷结构与性能的影响[J].稀有金属材料与工程,2018,47(S1):147~150.[Wu Linghao, Cuiwei Li, Xue Tian, Chang, an Wang. Effects of foaming agent Content on the Structure and Properties of PorousAnorthite Ceramics[J]. Rare Metal Materials and Engineering,2018,47(S1):147~150.]
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  • 收稿日期:2017-06-05
  • 最后修改日期:2018-01-31
  • 录用日期:2018-02-01
  • 在线发布日期: 2018-10-22
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