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Aurivillius型钛酸铋钠的低温合成及电性能研究
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华南理工大学,华南理工大学,华南理工大学

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广东省科技计划项目(No. 2007A010500012,2013A011401010)


Synthesis and electrical properties of Aurivillius-type sodium bismuth titanate at low temperatures
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South China University of Technology,South China University of Technology,South China University of Technology

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    摘要:

    以分析纯的Bi(NO3)3.5H2O、Ti(C4H9O)4和CH3COONa?3H2O为反应起始原料,通过两次水热法制备Aurivillius型钛酸铋钠(Na0.5Bi4.5Ti4O15,NBT),采用XRD和SEM研究两次水热条件所合成粉体的晶相组成和形貌,并测量了所得陶瓷的显微结构和电性能。研究表明,水热法所得纳米粉体由粒径~1.0μm、平均厚度<100nm的片状颗粒堆积而成,且各元素之比非常接近于NBT的化学计量比。NBT纳米粉体的合成温度低至260~270℃,是已公开报道文献中的最低温度。与传统固相烧结法所得NBT陶瓷相比较,用该水热粉体所得陶瓷具有非常相近的居里温度(≈674℃),且瓷体致密、细晶(<2μm),高温介电性能获得明显改善。

    Abstract:

    The Aurivillius-type sodium bismuth titanate (Na0.5Bi4.5Ti4O15 or NBT) powders were prepared by two-step hydrothermal routes with starting chemicals containing Bi(NO3)3?5H2O, Ti(C4H9O)4 and CH3COONa?3H2O. Crystalline phase and morphology of hydrothermally derived powders are investigated by XRD and SEM, and microstructure and electrical properties of derived ceramics are measured. The results indicate that the elemental ratio in the composition of hydrothermally derived nanopowders is very close to stoichiometic ratio of NBT, which possessed an average diameter of about 1.0μm and a thickness of less than 100 nm. The synthesis temperatures of NBT nanopowders are as low as 260~270℃, which is the lowest temperature among those published literatures. Compared with NBT ceramics by solid state sintering process, the ceramics resulting from hydrothermally derived powders, with dense ceramic body and fine grain size (<2μm), have very similar Curie temperature (≈674℃) and improved dielectric properties at high temperature.

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樊娇娇,何新华,陈丹玲. Aurivillius型钛酸铋钠的低温合成及电性能研究[J].稀有金属材料与工程,2018,47(S2):213~217.[Fan Jiao-jiao, He Xin-hua, Chen Dan-ling. Synthesis and electrical properties of Aurivillius-type sodium bismuth titanate at low temperatures[J]. Rare Metal Materials and Engineering,2018,47(S2):213~217.]
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  • 收稿日期:2017-11-29
  • 最后修改日期:2017-11-29
  • 录用日期:2018-02-01
  • 在线发布日期: 2018-11-01
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