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原位氧化工艺制备Ag-92SnO2In2O3电接触材料研究
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浙江大学,浙江大学,浙江大学,浙江大学,温州宏丰电工合金股份有限公司,温州宏丰电工合金股份有限公司,温州宏丰电工合金股份有限公司

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(浙江省科技计划项目,项目号2017C01051;浙江省自然科学基金,LQ17E010002)


Study on Ag-92SnO2In2O3electrical contacts fabricated by In-Situoxidation process
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Zhejiang University,Zhejiang University,Zhejiang University,Zhejiang University,Wenzhou Hongfeng Electrical Alloy Co Ltd,Wenzhou Hongfeng Electrical Alloy Co Ltd,Wenzhou Hongfeng Electrical Alloy Co Ltd

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    摘要:

    以Ag-65SnIn-8熔炼雾化粉体为原料,采用原位氧化工艺制备了Ag-60SnO2In2O3中间体粉体,与雾化纯银粉配比成Ag-92SnO2In2O3材料,通过混粉-等静压-烧结-热压-挤压技术制备Ag-92SnO2In2O3带材,再通过固相复合工艺制备所需要的Ag-92SnO2In2O3/Cu/Fe电接点材料。相对比常规氧化工艺制备的Ag-60SnO2In2O3中间体粉体制备的Ag-92SnO2In2O3/Cu/Fe电接点材料,原位氧化工艺制备的Ag-92SnO2In2O3/Cu/Fe电接点材料电阻率可达2.1μΩ.cm以下,硬度可达85~110HV;产品应用于380V,65A,功率因数0.7的电动机负载电路的热保护器中,电器寿命满足5000次分断要求,替代AgCdO/Cu/Fe电接点材料,实现环保,无镉化切换。

    Abstract:

    Intermediate Ag-60SnO2In2O3powders were synthesized by in-situ oxidation and traditional oxidation process with Ag-65SnIn-8 melting atomization powder as raw material, Ag-92SnO2In2O3materials were prepared by mixing-isostatic press and sintering-Hot extrusion technology, and then Ag-92SnO2In2O3/Cu/Fe contacts were fabricated by the solid phase bonding process.Compared with that synthesized by traditional oxidation process, Ag-92SnO2In2O3/Cu/Fe contacts fabricated with in-situ oxidated Ag-60SnO2In2O3 as reinforcing phase had lower electrical resistivity ( 2.1 μΩ.cm) and proper hardness(85~110HV). By installing the contacts in motor loaded-thermal protection circuit ( power factor 0.7, 380V, 65A), the results of eletrical life testing showed that Ag-92SnO2In2O3 electrical contacts fabricated by In-Situ oxidation process had higher operations(>5000 times) which was met the requirements and could substitute for AgCdO/Cu/Fe electrical contacts.

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吴新合,张玲洁,杨辉,樊先平,祁更新,陈晓,张宇星.原位氧化工艺制备Ag-92SnO2In2O3电接触材料研究[J].稀有金属材料与工程,2018,47(S2):31~34.[Wu Xinhe, Zhang Lingjie, Yang Hui, Fan Xianping, Qi Gengxin, Chen Xiao, Zhang Yuxing. Study on Ag-92SnO2In2O3electrical contacts fabricated by In-Situoxidation process[J]. Rare Metal Materials and Engineering,2018,47(S2):31~34.]
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  • 收稿日期:2017-12-12
  • 最后修改日期:2017-12-12
  • 录用日期:2018-02-01
  • 在线发布日期: 2018-11-01
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