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纳米晶W-La2O3电极材料的形成与烧结行为
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TG146.4

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国家自然科学基金资助项目(50071043)


Preparation and Sintering Behavior of Nanocrystalline W-La2O3 Electrode Materials
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    摘要:

    通过高能球磨将一定成分的W,La2O3粉研磨成纳米粉,在真空热压炉中将其烧结为块体的纳米晶电极材料。利用X射线衍射仪(XRD)、透射电镜(TEM)和扫描电镜(SEM)等手段分析晶粒的变化情况。结果表明,烧结的致密化主要在于纳米颗粒的重排,而不是传统的扩散;烧结过程中出现晶粒长大现象,但长大有限;机械研磨产生的内应变、某些杂质元素的存在等对烧结有促进作用。

    Abstract:

    Nanostructured W-La 2 O 3 composite powder was prepared by the high energy ball milling,or mechani ca l alloying(MA).Serially W-La 2 O 3 electrode materials were fabricate d by hot pressed sintering in vacuum .In each case the nanostructural evolutions was observed as function of milling tim e and sintering temperature using SEM,XRD and TEM.The results show that the si ntering densification depends on nanosize particle rearrangement ra sther than c onventional diffusion.The enhanced sinterability of MA W-L a 2 O 3 composite powder is attributed to their ultra-fine and homogeneously mixed state,high internal strain,as well as the sintering activation by impurity ele ments.

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陈文革 丁秉均 张晖.纳米晶W-La2O3电极材料的形成与烧结行为[J].稀有金属材料与工程,2003,(9):752~755.[Chen Wenge, Ding Bingjun, Zhang Hui. Preparation and Sintering Behavior of Nanocrystalline W-La2O3 Electrode Materials[J]. Rare Metal Materials and Engineering,2003,(9):752~755.]
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  • 最后修改日期:2002-02-04
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