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液相渗入-反应法制备木材结构SiC的研究
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TB383

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国家自然科学基金资助项目(50272051)


Preparation of Biomorphic SiC-Ceramics by the Reactive Infiltraion of Si into Carbon Template Derived from Basswood
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    摘要:

    椴木经高温炭化转变为木炭,经熔融硅反应性渗入后,生成具有椴木微观结构的多孔SiC陶瓷。借助TGA(采用Rigaku Thermal型热分析仪)研究了椴木的热分解行为,用XRD和SEM研究了椴木木炭和多孔SiC陶瓷的物相组成和微观结构,还探讨了Si向木炭中渗入.反应动力学和多孔SiC的基本性能。结果显示,木炭为无定形的非晶碳材料,多孔SiC由主晶相β-SiC和少量未反应C组成的;多孔SiC具有椴木的管胞结构,与木炭相比,力学性能得到显著改善;碳纤维向SiC纤维的转化及其对裂纹萌生、扩展的抑制作用和偏转作用是提高力学性能的主要机制。

    Abstract:

    Basswood was transformed by high-temperature pyrolysis into carbon performs (charcoal) and subsequently converted into cellular SiC-ceramics possessing pseudomorphous microstructure by the reactive-infiltration of Si into CB-template in Ar atmos- phere.Thermogravimetric analysis (TGA) was applied to reveal the pyrolysis behavior of basswood powder.Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were employed to characterize and analyze the microstructures and phase identification of CB-template and final SiC ceramics.The infiltration mechanism of liquid Si into charcoal and the basic properties of cellular SiC were also given.The results showed that CB-template was amorphous carbon materials.Final cellular SiC was composed of the major phase ?-SiC and a little unreacted carbon.Compared to charcoal,cellular SiC possessed higher mechanical properties.The improvement of the mechanical properties of materials was mainly caused by the following factors:one was the conversion of carbon fibres into SiC fibres,and the another was the volume expansion during CB-template-to-cellular SiC conversion,which inhibited the initiation and propagation of cracks and made cracks deflect.

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钱军民 王继平 金志浩.液相渗入-反应法制备木材结构SiC的研究[J].稀有金属材料与工程,2004,33(10):1065~1068.[Qian Junmin, Wang Jiping, Jin Zhihao. Preparation of Biomorphic SiC-Ceramics by the Reactive Infiltraion of Si into Carbon Template Derived from Basswood[J]. Rare Metal Materials and Engineering,2004,33(10):1065~1068.]
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  • 最后修改日期:2003-02-25
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