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Ni-Fe-Ga-Co磁性记忆合金微观组织与力学行为
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国家自然科学基金项目(50131010)


Microstructure and Mechanical Properties of Ni-Fe-Ga-Co Ferromagnetic Shape Memory Alloys
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    摘要:

    系统研究Ni-Fe-Ga-Co磁性形状记忆合金的显微组织结构以及力学行为,阐明掺Co对NiFeGa合金中γ相析出的影响规律,探明γ相增韧的微观机制。结果表明,铸态Ni-Fe-Ga-Co合金室温组织由马氏体和γ相两相组成,γ相数量随Co含量增加而增多。Fe和Co原子在马氏体相中存在最大饱和浓度,当二者含量之和超过16 at%时,剩余的Fe和Co原子以γ相形式析出。γ相为富Fe和Co而贫Ga相,且Fe和Co原子的最大饱和浓度约为23 at%。合金的屈服强度和断裂强度随Co含量增多呈增大趋势。断口观察发现,基体相为解理断裂,小尺寸的γ相被裂纹绕过或被整体拔出,大尺寸的γ相被拉长、撕裂或整体拔出,说明γ相有利于改善合金韧性,但增韧效果受到γ相尺寸的影响

    Abstract:

    The microstructure and mechanical properties of Ni56Fe17Ga27-xCox(x=0, 2, 4, 6) magnetic shape memory alloys have been studied, and the influence of Co addition on γ phase and the mechanism for increasing toughness by γ phase were revealed. The results show that the microstructure of as-melted alloys is composed of martensite phase and γ phase at room temperature. With increasing Co content, the volume of γ phase increases. For the martensite phase, the saturation solubility of Fe and Co atoms is fixed. If the total content of Fe and Co atoms exceeds 16 at %, the residual atoms will exist in the form of γ phase, which is rich in Fe and Co atoms. Besides, the saturation solubility of Fe and Co atoms in γ phase is around 23 at %. The tensile tests show that the yielding strength and fracture strength increase with increasing Co content. The fracture mechanism of martensite phase is transcrystalline fracture, and the γ phase is gliding fracture, it proves that the γ phase improves the toughness of experimental alloys

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高智勇,隋解和,李 民,余彗茹,蔡 伟. Ni-Fe-Ga-Co磁性记忆合金微观组织与力学行为[J].稀有金属材料与工程,2009,38(2):323~326.[Gao Zhiyong, Sui Jiehe, Li Min, Yu Huiru, Cai Wei. Microstructure and Mechanical Properties of Ni-Fe-Ga-Co Ferromagnetic Shape Memory Alloys[J]. Rare Metal Materials and Engineering,2009,38(2):323~326.]
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  • 收稿日期:2008-01-24
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