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SmCo1-xFexAsO的多重磁性转变
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国家磁约束核聚变能研究专项(2011GB112001);国际合作项目(2013DFA51050);国家自然科学基金(11104224,11004162,51271155);高等学校博士学科点专项科研基金新教师类课题(20110184120029);四川省科技计划项目(2011JY0031,2011JY0130);中央高校基本科研业务费专项资金(SWJTU11BR063)


Multiple Magnetic Transitions in SmCo1-xFexAsO
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    摘要:

    采用固相反应法,制备出一系列 SmCo1-xFexAsO(x = 0,0.05,0.1,0.2)多晶样品。XRD测试结果表明所有样品均为单相,且具有ZrCuSiAs型四方结构,随着掺杂量的增加,晶格参数a逐渐减小,c逐渐增加。磁性测量结果表明,低掺杂量样品在5 ~ 300 K之间先后经历了反铁磁-铁磁-顺磁的磁性转变,低场下的M - T曲线表现出明显的不可逆性,且随着掺杂量的增加,反铁磁转变温度降低,铁磁转变温度向高温方向移动,表明样品的反铁磁性逐渐被抑制,而铁磁性逐渐增强。M - H曲线表明,在反铁磁转变温度以下,掺杂量x < 0.2的样品,随着磁场的增加发生了由反铁磁到铁磁性的变磁性转变,且随着掺杂量的增加,在同一温度下的转变磁场变小。在掺杂量x = 0.2时,当温度降低到5 K时仍没有观察到变磁性转变,在掺杂量x = 0.2附近可能存在变磁性临界终点。

    Abstract:

    A series of polycrystalline sample SmCo1-xFexAsO (x=0, 0.05, 0.1, 0.2) was prepared by a solid-state reaction method. X-ray diffraction patterns indicate that all the samples have formed the ZrCuSiAs-type structure. The decrease of the lattice constant a and the increase of c are observed with the increased doping amount. Magnetic measurement results show that complicated magnetism consists of antiferromagnetic, ferromagnetic and paramagnetic between 5 and 300 K. Strong irreversibility in M-T curve is observed just below the Curie temperature. With Fe content increasing, antiferromagnetic order of SmCoAsO is suppressed, and its ferromagnetism is enhanced. M-H curves show that metamagnetic transition occurs below their antiferromagnetic transition temperature for samples with x<0.2, and the transition field decreases with increasing Fe content. When Fe content reaches to 0.2, no metamagnetic transition can be observed down to 5 K. All of the results are consistent with the existence of a metamagnetic critical end point at critical concentration which is close to 0.2.

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苏春燕,陈永亮,周大进,王小峰,李平原,崔雅静,赵 勇. SmCo1-xFexAsO的多重磁性转变[J].稀有金属材料与工程,2014,43(10):2431~2434.[Su Chunyan, Chen Yongliang, Zhou Dajin, Wang Xiaofeng, Li Pingyuan, Cui Yajing, Zhao Yong. Multiple Magnetic Transitions in SmCo1-xFexAsO[J]. Rare Metal Materials and Engineering,2014,43(10):2431~2434.]
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  • 收稿日期:2013-10-25
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  • 在线发布日期: 2015-04-07
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