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低温磁控溅射制备AZO薄膜及绒面研究
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浮法玻璃新技术国家重点实验室;蚌埠玻璃工业设计研究院,浮法玻璃新技术国家重点实验室;蚌埠玻璃工业设计研究院,浮法玻璃新技术国家重点实验室;蚌埠玻璃工业设计研究院,浮法玻璃新技术国家重点实验室;蚌埠玻璃工业设计研究院,浮法玻璃新技术国家重点实验室;蚌埠玻璃工业设计研究院,浮法玻璃新技术国家重点实验室;蚌埠玻璃工业设计研究院

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O484.4

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中国建筑材料集团有限公司集团经费资助


Study on Preparation and Their Textured Structures of AZO Thin Films by Magnetron Sputtering at Low Temperature
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State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry,State Key Laboratory of Advanced Technology for Float Glass;Bengbu Design & Research Institute for Glass Industry

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    摘要:

    本文采用直流射频耦合磁控溅射技术,以AZO(2 wt % Al2O3 )陶瓷靶为靶材,在玻璃基片上低温沉积AZO薄膜,并采用质量分数为0.5%的HCl溶液刻蚀制备绒面AZO薄膜,通过XRD、SEM、分光光度计、霍尔效应测试系统、光电雾度仪等设备重点研究工作压强对直流射频耦合磁控溅射制备AZO薄膜的晶相结构、表面形貌、光电性能以及后期制绒的影响。研究表明,直流射频耦合磁控溅射可以在低温下制备性能优异的AZO薄膜,且随着工作压强的减少,致密性增加,光电性能改善,后期刻蚀得到具有良好陷光作用的绒面结构。在工作压强0.5Pa下,低温制备的AZO薄膜电阻率达到3.55?0-4Ω?cm,薄膜可见光透过达到88.36%,刻蚀后电阻率为4.19?0-4Ω?cm,可见光透过率89.59%,雾度达24.7%。

    Abstract:

    The AZO films were deposited on glass substrates by DC coupled RF magnetron sputtering at low temperature with a AZO ceramic target(2 wt % Al2O3) , and then AZO films were etched by the mass fraction of 0.5% HCl solution to obtain textured structures. Crystal phase structure, surface morphology, optical, electrical properties and the textured structure of AZO films mainly influenced by working pressure were characterized by XRD, SEM, spectrophotometer, hall effect test system and photoelectric haze instrument respectively. The results show that AZO thin films with excellent performance can be prepared by DC coupled RF magnetron sputtering at low temperatures. With the decrease of working pressure, the compactness of AZO films is increased, and their photoelectric performance improves, and textured structures with good light trapping effect can be obtained by post etching. Under working pressure of 0.5 Pa, the resistivity of AZO thin films prepared at low temperature is 3.55?0-4 Ω?cm, and the transmittance at visible light is 88.36%. After etching, their resistivity and transmittance at visible light are 4.19?0-4 Ω?cm and 89.59% respectively, and the haze reaches to 24.7%.

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张宽翔,彭寿,姚婷婷,曹欣,金克武,徐根保.低温磁控溅射制备AZO薄膜及绒面研究[J].稀有金属材料与工程,2017,46(3):818~823.[Zhang Kuanxiang, Peng Shou, Yao Tingting, Cao Xin, Jin Kewu, Xu Genbao. Study on Preparation and Their Textured Structures of AZO Thin Films by Magnetron Sputtering at Low Temperature[J]. Rare Metal Materials and Engineering,2017,46(3):818~823.]
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  • 收稿日期:2014-11-24
  • 最后修改日期:2014-12-18
  • 录用日期:2015-03-25
  • 在线发布日期: 2017-05-18
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