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固溶处理态Mg-Nd-Gd-Sr-Zn-Zr生物镁合金的组织与均匀腐蚀行为
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南京工程学院 材料工程学院,南京工程学院 材料工程学院,南京工程学院 材料工程学院,南京工程学院 材料工程学院,江苏康尚医疗器械有限公司

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国家自然科学(51301089),江苏省自然科学(BK20130745),江苏省“青蓝工程”资助项目,南京工程学院大学生科技创新项目(N20150241)


Microstructure and uniform corrosion behaviour of solution treated Mg-Nd-Gd-Sr-Zn-Zr bio-magnesium alloys
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School of Materials Science and Engineering,Nanjing Institute of Technology,Nanjing,School of Materials Science and Engineering,Nanjing Institute of Technology,Nanjing,School of Materials Science and Engineering,Nanjing Institute of Technology,Nanjing,School of Materials Science and Engineering,Nanjing Institute of Technology,Nanjing,Jiangsu Konsung Equipment Co,Ltd

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    摘要:

    对Mg-(4-x)Nd-xGd-0.3Sr-0.2Zn-0.4Zr(质量分数,%,x=0, 1和3)镁合金进行了固溶处理。采用扫描电镜、能谱分析仪和X射线衍射仪研究了合金的显微组织与物相。利用失重和析氢法测试了合金在模拟体液中的腐蚀速率,并观察了合金的腐蚀形貌。结果表明,含1%Gd的合金晶粒最细小,且第二相较为连续地分布在基体周围,腐蚀速率也最低;而含3%Gd的合金晶粒最粗大,腐蚀速率最快。3种合金的腐蚀形貌较为均匀,是理想的生物可降解材料。

    Abstract:

    Solution treatment was conducted on Mg-(4-x)Nd-xGd-0.3Sr-0.2Zn-0.4Zr(mass fractuon, %, x=0, 1, 3). The microstructures and phases were studied using scanning electron microscope (SEM), energy dispersive spectrometer and X-ray diffraction. The corrosion rates of the alloys in simulated body fluid were evaluated by mass loss and hydrogen evolution tests, and the corrosion morphologies of the alloys were observed by SEM. It is found that the grain size of the alloy with 1%Gd addition is the finest, as well as the lowest corrosion rate, and the second phase was located relatively continuously around the matrix. While the grain size of the alloy with 3%Gd addition is the coarsest and the corrosion rate is the highest. The alloys exhibit relatively uniform corrosion morphologies, and thus, they are desirable biodegradable materials.

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章晓波,马青龙,巴志新,王章忠,王强.固溶处理态Mg-Nd-Gd-Sr-Zn-Zr生物镁合金的组织与均匀腐蚀行为[J].稀有金属材料与工程,2017,46(4):1156~1161.[Zhang Xiaobo, Ma Qinglong, Ba Zhixin, Wang Zhangzhong, Wang Qiang. Microstructure and uniform corrosion behaviour of solution treated Mg-Nd-Gd-Sr-Zn-Zr bio-magnesium alloys[J]. Rare Metal Materials and Engineering,2017,46(4):1156~1161.]
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  • 收稿日期:2014-12-18
  • 最后修改日期:2015-03-16
  • 录用日期:2015-04-24
  • 在线发布日期: 2017-08-04
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