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Zn对粉末冶金法制备Mg-Zn合金组织与性能的影响
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辽宁工业大学材料科学与工程学院,辽宁工业大学材料科学与工程学院,辽宁工业大学材料科学与工程学院,辽宁工业大学材料科学与工程学院,辽宁工业大学材料科学与工程学院,东北大学

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Effect of Zn on microstructure and properties of Mg-Zn alloys prepared by powder metallurgy method
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    摘要:

    以Mg粉和Zn粉为初始原料,采用粉末冶金技术制备Mg-Zn合金。研究了Zn含量对Mg-Zn合金烧结密度、显微组织、物相组成、弯曲强度和显微硬度的影响。测量了Mg-Zn合金的耐腐蚀性,探讨了Zn元素在粉末冶金过程中的作用机理。研究结果表明当添加Zn元素后,烧结产物的晶粒细小,烧结密度提高。此外,随着Zn含量的增加,烧结产物的致密度持续增加。XRD分析表明Mg-3 wt%Zn合金主要由α-Mg相组成,而Mg-4 wt%Zn合金由α-Mg 和 MgZn2两相组成。随着Zn含量的增加,Mg-Zn合金的弯曲强度先增加而后降低,但是显微硬度持续增加。Mg-3 wt% Zn合金的抗弯强度为123.6 MPa,显微硬度为101.7 HV,分别为纯Mg样品高出58%和45%。耐腐蚀性能测试表明当添加Zn元素后,Mg-Zn合金的腐蚀速率降低,Mg-3 wt%Zn合金具有最低的腐蚀速率和最佳的耐腐蚀性能。

    Abstract:

    Mg-Zn alloys were prepared by powder metallurgy method using Mg powder and Zn powder as initial materials. The effects of the Zn content on sintering density, microstructure, phase composition, bending properties and micro-hardness of the Mg-Zn alloys were studied. The corrosion resistance of the Mg-Zn alloys was also measured. The function mechanism of Zn element during the powder metallurgy process was analyzed. It is shown that the sintered compacts have finer grain size and higher sintered density upon Zn addition. The density of the sintered products increases with increasing Zn contents. XRD analysis shows the Mg-3 wt% Zn alloy is mainly composed of α-Mg phase. When the content of Zn is 4 wt%, the Mg-Zn alloys are composed of α-Mg and MgZn2 phases. With the increase of the Zn content, the bending strength of the Mg-Zn alloys first increases and then decreases, but the micro-hardness of Mg-Zn alloys always increases. The bending strength and micro-hardness of Mg-3 wt% Zn alloys are 123.6 MPa and 101.7 HV, respectively, which are 58% and 45% higher than those of pure Mg samples. Corrosion resistance measurements show that the corrosion rate of the Mg-Zn alloys decreases with the addition of Zn element, with the Mg-3 wt% Zn alloy showing the lowest corrosion rate and best corrosion resistance.

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于景媛,王建中,李强,张峰峰,曹健铭,孙旭东. Zn对粉末冶金法制备Mg-Zn合金组织与性能的影响[J].稀有金属材料与工程,2016,45(11):2757~2762.[yujingyuan, Wang Jian-zhong, Li Qiang, Zhang Feng-feng, Cao Jian-ming, Sun Xu-dong. Effect of Zn on microstructure and properties of Mg-Zn alloys prepared by powder metallurgy method[J]. Rare Metal Materials and Engineering,2016,45(11):2757~2762.]
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  • 收稿日期:2015-01-12
  • 最后修改日期:2015-02-09
  • 录用日期:2015-03-25
  • 在线发布日期: 2016-12-08
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