李哲楠,赵玉,李鹏,杨胜翔,王立章.十二烷基硫酸钠对IrO2-Ta2O5/SnO2- Sb-Mn/Ti电极电催化性能影响[J].稀有金属材料与工程,2017,46(10):2963~2968.[lizhenan,zhaoyu,lipeng,yangshengxiang,wanglizhang.Effect of Sodium dodecyl sulfate on IrO2 - Ta2O5 / SnO2 - Sb - Mn/Ti electrode electric catalytic performance[J].Rare Metal Materials and Engineering,2017,46(10):2963~2968.]
十二烷基硫酸钠对IrO2-Ta2O5/SnO2- Sb-Mn/Ti电极电催化性能影响
投稿时间:2015-06-23  修订日期:2015-09-26
中文关键词:  十二烷基硫酸钠,IrO2-Ta2O5/SnO2- Sb-Mn/Ti,电催化氧化,苯酚
基金项目:江苏省基础研究计划(自然科学基金)资助项目(BK2011224); 中央高校基本科研业务费专项资金资助项目(2013QNA20)
中文摘要:
      采用涂刷-热分解法制备不同浓度阴离子表面活性剂十二烷基硫酸钠(SDS)的IrO2-Ta2O5/SnO2- Sb-MnO2/Ti电极,通过扫描电子显微镜(SEM)和X射线衍射仪(XRD)对其微观形貌及物相组成进行分析;应用循环伏安、极化等测试手段,表征制备电极的电催化活性.结果表明,适量添加十二烷基硫酸钠能够改善IrO2-Ta2O5/SnO2-Sb-Mn/Ti电极的微观形貌,提高电催化活性.在本实验条件下,SDS最佳添加量是1.6 g/L,结晶化度高达99.83%.利用苯酚电催化降解实验和强化寿命测试进一步考察所制电极的电催化活性与稳定性,结果显示,在电流密度15 mA/cm2条件下电解180 min,SDS的加入使苯酚去除率由原来的68.5%提高到79.2%.COD去除率由60.1%提高到 67.5%,电催化性能得到提升,电极强化寿命由52 h延长至68 h.
Effect of Sodium dodecyl sulfate on IrO2 - Ta2O5 / SnO2 - Sb - Mn/Ti electrode electric catalytic performance
英文关键词:Sodium dodecyl sulfate (SDS)  IrO2 - Ta2O5 / SnO2 - Sb - Mn/Ti  Electrocatalytic oxidation  phenol
英文摘要:
      In this paper, an anionic surfactant, i.e. sodium dodecyl sulfate (SDS) was employed for preparation of the IrO2-Ta2O5/SnO2-Sb-MnO2/Ti electrodes through the pyrolysis process. The microstructure and phase composition of the electrodes were analyzed via scanning electron microscopy (SEM) and X-ray diffraction (XRD), and the cyclic voltammetry (CV) and polarization curves were also measured to evaluate their electro-catalytic activity by using an electrochemical station (type CS310). The obtained results revealed that the employment of the SDS could effectively improve the microstructure as well as enhance the electro-catalytic ability of the electrodes. Under the conditions of this study, the optimum dosage of SDS was 1.6 g/L for preparation of the IrO2-Ta2O5/SnO2-Sb-MnO2/Ti electrodes and the crystallization degree as high as 99.83% could be obtained. The electrode performances and stability were further investigated by anodic oxidation of phenol and accelerated life test. The experimental data depicted the phenol and chemical oxygen demand (COD) removal efficiency were increased from 68.5% and 60.1% to 79.2% and 67.5% when electrodes without and with dosage of 1.6 g/L were used, respectively, for phenol degradation at conditions of current density of 15 mA/cm2 and reaction time of 180 min; moreover, the accelerated life were raised to 68 h, which is much longer than that of the former (52 h).
作者单位E-mail
李哲楠 中国矿业大学环境与测绘学院 zhenanlicumt@163.com 
赵玉 杭州至美环境科技有限公司  
李鹏 东华理工大学  
杨胜翔 中国矿业大学环境与测绘学院  
王立章 中国矿业大学环境与测绘学院 wlzh0731@126.com 
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