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等离子喷涂TiC/ZrO2复相涂层的抗烧蚀性能研究
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北京理工大学材料学院,北京理工大学材料学院,北京理工大学材料学院,北京理工大学材料学院

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Ablation resistance property of TiC/ZrO2 coating deposited by plasma-spraying
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School of Material Science and Engineering,Beijing Institute of Technology,Beijing,School of Material Science and Engineering,Beijing Institute of Technology,Beijing,School of Material Science and Engineering,Beijing Institute of Technology,Beijing,School of Material Science and Engineering,Beijing Institute of Technology,Beijing

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    摘要:

    针对TiC涂层在高温烧蚀过程中氧化生成熔融TiO2。当温度高于2000℃时,熔融TiO2的厚度随之增加,这将进一步导致涂层结合强度降低,本文采用等离子喷涂方法制备了不同ZrO2添加量的TiC/ZrO2复相涂层,以提高涂层的抗冲刷性能。分别利用XRD、SEM和EDS对烧蚀前后材料的相结构、微观形貌和成分进行了分析,探讨了添加高熔点相ZrO2的复合涂层的抗烧蚀机理。结果表明:TiC/ZrO2复相涂层展现出更好的抗烧蚀性能,2000℃下的质量烧蚀率仅为1.5×10-4 g.cm-2.s-1。烧蚀过程中产生的ZrO2层可以阻止内部TiC的进一步氧化,并且可以在一定程度上降低氧乙炔焰对涂层的产生的剪切力,以提高涂层的康冲刷性能。

    Abstract:

    In high temperature ablation process, the TiC coating will be oxidized to TiO2. The thickness of molten TiO2 increases when the temperature is higher than 2000℃, which decreases the bonding strength of coating. In this study, the TiC/ZrO2 coatings with different content of high melting phase ZrO2 were deposited by plasma spraying, in order to improve the anti-scouring property of TiC coatings. The phase structure, microstructure and composition of coatings, before and after ablation, were characterized by XRD, SEM and EDS, respectively. The ablation resistant mechanism of coatings with high melting phase ZrO2 was discussed. The results indicate that the TiC/ZrO2 coating shows good ability of ablation resistance, and its weight loss is only 1.5×10-4 g.cm-2.s-1 at 2000℃. The ZrO2 layer formed during the ablation can restrain the further oxidation of inner TiC and reduce the shearing force of oxyacetylene flame, which improves the anti-scouring property of coatings.

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马壮,李文智,高丽红,文波.等离子喷涂TiC/ZrO2复相涂层的抗烧蚀性能研究[J].稀有金属材料与工程,2017,46(8):2097~2101.[Ma Zhuang, Li Wenzhi, Gao Lihong, Wen Bo. Ablation resistance property of TiC/ZrO2 coating deposited by plasma-spraying[J]. Rare Metal Materials and Engineering,2017,46(8):2097~2101.]
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  • 收稿日期:2015-07-24
  • 最后修改日期:2015-10-24
  • 录用日期:2015-11-18
  • 在线发布日期: 2017-11-16
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