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W-Ni-Cu 和W-Ni-Fe合金的腐蚀性能
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曼彻斯特大学,曼彻斯特大学,曼彻斯特大学

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Corrosion Performance of W-Ni-Cu and W-Ni-Fe Alloys
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University of Manchester,,

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    摘要:

    高比重钨合金是一种具有高密度,高机械强度和良好的耐腐蚀性等特性的复合材料,并广泛应用于工业和军事中。本文采用沉浸实验和电化学实验对两种钨合金(90%W-6%Ni-4%Cu和95%W-3.5%Ni-1.5%Fe)的腐蚀性能进行了研究。结果的表明,当W-Ni-Cu合金发生电偶腐蚀时,W相首先遭到腐蚀,而在W-Ni-Fe合金中,粘结相会先发生腐蚀。电动位极化测量结果表明pH值对高比重合金钨合金腐蚀速率有显著影响,与酸性环境相比较,合金在中性溶液中得到较低的腐蚀速率。根据SEM和EDX的结果分析了合金成分的溶解以及腐蚀产物的生成等腐蚀机理。

    Abstract:

    Tungsten heavy alloys (WHAs) achieve a special combination of properties, such as high density, high mechanical strength and good corrosion resistance in the industrial and military applications. In this study, the corrosion performance of two WHAs, 90%W-6%Ni-4%Cu and 95%W-3.5%Ni-1.5%Fe has been investigated by immersion test and electrochemical test. The AFM results indicated the attack would be on the W phase in W-Ni-Cu alloy when it generated galvanic corrosion, W-Ni-Fe alloy revealed opposite result. Potentiodynamic polarization measurement showed pH value is an important factor in corrosion rate. The two types alloys showed relatively lower corrosion rates in DI water, as compared to 0.6MHCl solution. The corrosion mechanism was involved in the release of the metallic components and generation of corrosion products in term of SEM and EDX.

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李鹭,Zhu Liu,刘玉项. W-Ni-Cu 和W-Ni-Fe合金的腐蚀性能[J].稀有金属材料与工程,2018,47(6):1708~1715.[li lu, zhu liu, liu yu xiang. Corrosion Performance of W-Ni-Cu and W-Ni-Fe Alloys[J]. Rare Metal Materials and Engineering,2018,47(6):1708~1715.]
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  • 收稿日期:2017-12-22
  • 最后修改日期:2018-02-02
  • 录用日期:2018-03-12
  • 在线发布日期: 2018-09-06
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