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BN纤维束增强氮化物复合材料的制备与性能
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西北工业大学,西北工业大学,西北工业大学,西北工业大学,西北工业大学,山东工业陶瓷设计研究院

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国家自然科学基金资助(项目号51472201,51602258)


Preparation and Properties of BN Fiber Reinforced Nitride Mini-composites
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Northwestern Polytechnical University,,,,,

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    摘要:

    采用低压化学气相沉积/渗透法(LPCVD/CVI)制备了BNf/BN、BNf/SiBN和BNf/Si3N4纤维束复合材料,研究了BN纤维束及三种纤维束复合材料的微结构、拉伸性能和介电性能。结果显示,BN纤维是由晶化程度较低的h-BN组成,其相结构在制备温度下未发生变化。纤维的表面存在大量50-500nm的微孔缺陷。800 oC处理后纤维束的平均拉伸强度为94MPa。BNf/BN、BNf/SiBN以及BNf/Si3N4拉伸强度依次降低,平均值分别为68.8 MPa、30.6 MPa、26.2MPa,断裂模式均为脆性断裂。原因在于:纤维损伤随制备温度升高而加剧;纤维/基体模量失配,纤维不能有效承载;界面结合强度过高,裂纹不能有效偏转。三种纤维束复合材料的介电常数实部ε’<3.0,介电损耗tanδ<0.04,电磁透波性能良好,其中BNf/BN复合材料具有最佳的综合性能。

    Abstract:

    BNf/BN, BNf/SiBN and BNf/Si3N4 mini-composites were fabricated by Low pressure chemical vapor deposition/infiltration (LPCVD/CVI) process. The microstructure, tensile property and dielectric property of BN fiber bundle and these three mini-composites were investigated. Results indicated that BN fiber composed of h-BN with low crystallinity, phase structure of which unchanged after heat treatment at 650 oC and 800 oC. Amounts of micro pores with size of 50-500nm exist on the surface of BN fiber. Mean tensile strength of BN fiber bundle heat treated at 800 oC is 94 MPa. Average tensile strength of BNf/BN, BNf/SiBN and BNf/Si3N4 mini-composites were 68.8 MPa, 30.6 MPa and 26.2 MPa, respectively. Three mini-composites all exhibited brittle fracture behavior, owing to the modulus mismatch between fiber and matrix and strong interphase bond strength. Cracks cannot be effectively deflected and fibers cannot bear the load effectively. Real part of dielectric constant and dielectric loss were lower than 3 and 0.04, respectively, indicating good Electromagnetic wave transmitting property. BNf/BN possessed the best comprehensive performance.

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李建平,成来飞,叶昉,程赞粼,刘永胜,张铭霞. BN纤维束增强氮化物复合材料的制备与性能[J].稀有金属材料与工程,2018,47(9):2901~2908.[Li Jianping, Cheng Laifei, Ye Fang, Cheng Zanlin, Liu Yongsheng, Zhang Mingxia. Preparation and Properties of BN Fiber Reinforced Nitride Mini-composites[J]. Rare Metal Materials and Engineering,2018,47(9):2901~2908.]
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  • 收稿日期:2018-03-21
  • 最后修改日期:2018-05-18
  • 录用日期:2018-05-21
  • 在线发布日期: 2018-11-01
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