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YZr掺杂对CeFeB合金微观结构和磁性能的影响
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南昌航空大学 材料科学与工程学院,江西 南昌 330063

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基金项目:

国家自然科学基金项目(面上项目,重点项目,重大项目)


Effects of Y and Zr Doping on Microstructure and Magnetic Properties for CeFeB Alloy
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Affiliation:

School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China

Fund Project:

National Natural Science Foundation of China (51961027, 51564037, 51401103); Key Research and Development Program of Jiangxi Province (20181ACE50005, 20192ACB50020)

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    摘要:

    研究了Y和Zr掺杂对CeFeB合金相组成、磁性能和温度稳定性的影响。结果表明,CeYFeB合金由2:14:1主相和少量α-Fe相组成。Y掺杂可有效提高合金的矫顽力、剩磁和最大磁能积。同时由于Y2Fe14B相优异的磁性能与高温稳定性,其温度稳定性也得到明显改善,掺杂后合金的剩磁和矫顽力温度系数分别为-0.32%/K和-0.41%/K,与纯CeFeB合金相比分别提高了38.5%和40.6%。Y和Zr共掺杂后,由于增加的磁晶各向异性场和晶粒尺寸细化所产生的联合效应,合金的矫顽力、剩磁和最大磁能积大幅度提高,分别比纯CeFeB合金提高了30.9%、58.1%和204.8%。

    Abstract:

    Effects of Y and Zr doping on the phase constituent, magnetic properties, and temperature stability for CeFeB alloy were investigated. The results show that CeYFeB alloy consists of the 2:14:1 main phase and a small amount of α-Fe phase. Magnetic properties including coercivity, remanence, and magnetic product energy improve considerably after Y doping. Meanwhile, the temperature stability is enhanced significantly. Due to the excellent intrinsic magnetic properties and higher temperature stability of Y2Fe14B phase, the remanence and coercivity temperature coefficients are -0.32%/K and -0.41%/K, increasing by 38.5% and 40.6%, respectively, compared to those of the pure CeFeB alloy. After the Y and Zr co-doping, the coercivity, remanence, and magnetic product energy improve greatly, increasing by 30.9%, 58.1%, and 204.8%, respectively, compared to those of pure CeFeB alloy, because of the joint effects of enhanced magnet crystalline anisotropic field and refined grain size.

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周艳霞,李伟,符小坤,侯育花,黄有林.YZr掺杂对CeFeB合金微观结构和磁性能的影响[J].稀有金属材料与工程,2021,50(9):3139~3143.[Zhou Yanxia, Li Wei, Fu Xiaokun, Hou Yuhua, Huang Youlin. Effects of Y and Zr Doping on Microstructure and Magnetic Properties for CeFeB Alloy[J]. Rare Metal Materials and Engineering,2021,50(9):3139~3143.]
DOI:10.12442/j. issn.1002-185X.20200525

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历史
  • 收稿日期:2020-07-22
  • 最后修改日期:2020-08-19
  • 录用日期:2020-09-02
  • 在线发布日期: 2021-09-26
  • 出版日期: 2021-09-24