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电场对浮法玻璃与可伐合金4J29钎焊接头组织与性能的影响
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兰州理工大学 省部共建有色金属先进加工与再利用国家重点实验室

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国家自然科学基金(52061023)


Effect of electric field on the structure and properties of brazed joints of float glass and Kovar 4J29
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State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metal,Lanzhou University of Technology

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    摘要:

    本文采用ALTSAB技术,选用SnAg3.5Ti2钎料,实现了可伐合金4J29与浮法玻璃的有效连接。研究了电压、温度对界面微观结构和剪切强度的影响,并探究了连接形成的机制。研究结果表明:随着电压和温度的升高,玻璃与钎料界面平直无显著变化,界面形成新的化学键≡Si-O-Ti和≡Si-O-Sn,发生氧化反应生成TiO、SnO; 钎料与合金侧有反应溶解现象,可伐合金侧生成了FeSn2相,钎料中分布着一些细长棒状和针状的Ni3Sn4相,分析认为:钠离子耗尽层的产生以及Ti2+、Sn2+向玻璃基体中的扩散是形成有效连接的关键。接头剪切强度随电压和温度的升高而增大,当电压为1000V、温度400℃时,最大剪切强度为12.5Mpa。

    Abstract:

    In this paper, the effective connection between kovar alloy 4J29 and float glass was realized by using ALTSAB technology and SnAg3.5Ti2 solder. The effects of voltage and temperature on the interface microstructure and shear strength were studied, and the mechanism of bonding formation was explored. The results show that: with the increase of voltage and temperature, the interface between glass and solder has no significant change, new chemical bonds ≡Si-O-Ti and ≡Si-O-Sn are formed at the interface, and TiO and SnO are formed by oxidation reaction; there is reaction dissolution phenomenon between solder and alloy side, FeSn2 phase is formed at the kovar alloy side.There are some slender rod-shaped and needle-like Ni3Sn4 phases in the solder. It is considered that the formation of sodium ion depletion layer and the diffusion of Ti2+ and Sn2+ into the glass matrix are the key to the formation of effective bonding. The maximum shear strength is 12.5Mpa when the voltage is 1000V and the temperature is 400 ℃.

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俞伟元,杨国庆,孙学敏,王锋锋,张涛.电场对浮法玻璃与可伐合金4J29钎焊接头组织与性能的影响[J].稀有金属材料与工程,2021,50(11):4003~4009.[Yu Weiyuan, Yang Guoqing, Sun Xuemin, Wang Fengfeng, Zhang Tao. Effect of electric field on the structure and properties of brazed joints of float glass and Kovar 4J29[J]. Rare Metal Materials and Engineering,2021,50(11):4003~4009.]
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历史
  • 收稿日期:2020-11-08
  • 最后修改日期:2020-11-24
  • 录用日期:2020-12-23
  • 在线发布日期: 2021-11-30
  • 出版日期: 2021-11-24