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高剂量离子辐照效应对CdZnTe:In晶体光电性能的影响
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1.西北工业大学 材料学院 凝固技术国家重点实验室,陕西 西安 710072;2.西北工业大学 材料学院 辐射探测材料与器件工信部重点实验室,陕西 西安 710072

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国家重大科学仪器设备开发专项


High Dose Ion Beam Irradiation Effects on the Electrical and Optical Properties of CdZnTe:In Crystals
Author:
Affiliation:

1.State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China;2.Key Laboratory of Radiation Detection Materials and Devices, Ministry of Industry and Information Technology, School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China

Fund Project:

National Key Research and Development Program of China (2016YFF0101301); Supported by Heavy Ion Research Facility in Lanzhou (HIRFL)

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    摘要:

    研究了离子辐照效应对CdZnTe(CZT)晶体光电性能的影响。采用Ar离子对改进的垂直布里奇曼法生长的CZT晶体进行辐照,剂量范围为1014~1015 cm-2。红外透过光谱测试结果表明,辐照前晶体样品的高直型光谱转变为辐照后的上升性光谱。辐照诱导产生的高浓度自由载流子引起的光吸收在红外透过光谱的中红外范围内占主导地位。由于离子辐照发生在单侧照射面的近表面区域,辐照后晶体样品的I-V特性曲线变得极不对称。在负偏压的条件下,电流随着电压的增大而急剧增大。霍尔效应测试结果表明,辐照前晶体样品的净载流子浓度约为106 cm-3,而辐照后的净载流子浓度大幅增加,约为1016 cm-3。CZT晶体的导电类型在离子辐照前后并没有发生变化,施主缺陷能级在辐照诱导缺陷中占主导地位。

    Abstract:

    Effects of ion beam irradiation defects on electrical and optical properties of CdZnTe (CZT) crystals were studied. CZT crystals grown by the modified vertical Bridgman method were irradiated by Ar heavy ions with fluences ranging from 1014 cm-2 to 1015 cm-2. Results show that IR transmittance spectra vary from the high-straight type (before radiation) to the ascending type (after radiation), and light absorption by radiation induced free charge carriers occurs significantly in the mid-infrared light range. Current-voltage (I-V) characteristic curve of the irradiated CZT crystals becomes extremely asymmetrical and current increases sharply with the increase of negative voltage due to single-surface irradiation in the near-surface area. Hall measurements show that the net carrier concentration largely increases from ~106 cm-3 (before radiation) to ~1016 cm-3 (after radiation), and the conduction type remains unchanged, since donor levels are considered to be the dominant among all the radiation-induced crystal defects.

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徐凌燕,刘哲,梁璐.高剂量离子辐照效应对CdZnTe:In晶体光电性能的影响[J].稀有金属材料与工程,2021,50(6):1941~1945.[Xu Lingyan, Liu Zhe, Liang Lu. High Dose Ion Beam Irradiation Effects on the Electrical and Optical Properties of CdZnTe:In Crystals[J]. Rare Metal Materials and Engineering,2021,50(6):1941~1945.]
DOI:10.12442/j. issn.1002-185X.20200979

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历史
  • 收稿日期:2020-12-18
  • 最后修改日期:2021-02-05
  • 录用日期:2021-03-08
  • 在线发布日期: 2021-07-07
  • 出版日期: 2021-06-30