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LaAl添加对放电等离子烧结LaFeSi磁体微观结构和磁热效应的影响
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1.南昌航空大学 材料科学与工程学院,江西 南昌 330063;2.南昌航空大学 航空制造工程学院,江西 南昌 330063

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National Natural Science Foundation of China (Grant Nos. 51961027, 51564037 and 51401103), the Key Research and Development Program of Jiangxi Province (Grant Nos. 20181ACE50005 and 20192ACB50020) and the Postgraduate Innovation Special Fund of Jiangxi Province (YC2019005).;江西省重点研究计划;南昌航空大学研究生创新专项资金项目


Microstructure and Magnetocaloric Effect of Spark Plasma Sintered LaFeSi Magnets with LaAl Addition
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Affiliation:

1.School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China;2.School of Aeronautical Manufacturing Engineering, Nanchang Hangkong University, Nanchang 330063, China

Fund Project:

National Natural Science Foundation of China (51961027, 51564037, 51401103); Key Research and Development Program of Jiangxi Province (20181ACE50005, 20192ACB50020); Postgraduate Innovation Special Fund of Jiangxi Province (YC2019005)

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    摘要:

    使用LaFe11.3Si1.7薄带合金为前驱体粉末,研究了低熔点La0.77Al0.23合金添加对放电等离子烧结磁体微观结构和磁热性能的影响。研究发现,适量低熔点LaAl合金的添加能够促进包晶反应,制得了具有较高1:13相含量的LaFeSi磁体。磁体中观察到有微弱的巡游电子变磁转变现象的存在。热处理工艺研究显示,退火时间的增加会使得磁体的磁性转变由一级向二级变化,这主要归因于Al向1:13相内部的扩散。1000 ℃/6 h热处理工艺条件下,其在0~5 T磁场变化下的磁熵变最大,达12.40 J?kg-1?K-1,而1000 ℃/10 h条件下所获得磁体的制冷能力最强,为318.40 J?kg-1

    Abstract:

    Using LaFe11.3Si1.7 and La0.77Al0.23 alloys as precursors, the bulk LaFeSi samples with excellent magnetocaloric performance were synthesized through the spark plasma sintering (SPS) technology. The results show that the La0.77Al0.23 compound with a low melting point is helpful in facilitating peritectic reaction, and NaZn13-type phase with high content can be achieved. A slight itinerant-electron-metamagnetic transition is observed. The increased thermal annealing time facilitates magnetic transition from the first order to the second order, which is ascribed to the excessive Al diffusion into the 1:13 phase. Under the thermal treatment condition of 1000 °C/6 h, the maximum entropy change (-ΔSM) max of 12.40 J?kg-1?K-1 can be obtained, and the highest refrigerating capacity, up to 318.40 J?kg-1, is achieved under thermal annealing condition of 1000 °C/10 h.

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符小坤,舒嵘,侯育花,刘艳颖,黄有林,李伟,范文兵.LaAl添加对放电等离子烧结LaFeSi磁体微观结构和磁热效应的影响[J].稀有金属材料与工程,2022,51(4):1239~1244.[Fu Xiaokun, Shu Rong, Hou Yuhua, Liu Yanying, Huang Youlin, Li Wei, Fan Wenbing. Microstructure and Magnetocaloric Effect of Spark Plasma Sintered LaFeSi Magnets with LaAl Addition[J]. Rare Metal Materials and Engineering,2022,51(4):1239~1244.]
DOI:10.12442/j. issn.1002-185X.20210069

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  • 收稿日期:2021-01-22
  • 最后修改日期:2021-04-28
  • 录用日期:2021-05-12
  • 在线发布日期: 2022-04-28
  • 出版日期: 2022-04-28