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FeCoCrNiZr x 高熵合金的磁性和电化学性能
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作者单位:

1.安徽建筑大学 机械与电气工程学院,安徽 合肥 230601;2.工程机械智能制造重点实验室,安徽 合肥 230601

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中图分类号:

TG132.3+2

基金项目:

安徽省高等学校自然科学研究项目Natural Science Foundation of the Higher Education Institutions of Anhui Province, China (KJ2020ZD42)


Magnetic and Electrochemical Properties of FeCoCrNiZr x High-Entropy Alloys
Author:
Affiliation:

1.School of Mechanical and Electrical Engineering, Anhui Jianzhu University, Hefei 230601, China;2.Key Laboratory of Intelligent Manufacturing of Construction Machinery, Hefei 230601, China

Fund Project:

Natural Science Foundation of the Higher Education Institutions of Anhui Province, China (KJ2020ZD42)

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    摘要:

    采用真空电弧熔炼法制备了不同Zr含量的FeCoCrNiZrxx=0.5,0.75,1)高熵合金。研究了Zr含量对合金组织、磁性能和电化学腐蚀性能的影响。采用X射线衍射仪、扫描电镜、振动样品磁力计和电化学工作站对合金的磁性能和电化学腐蚀能力进行了研究。结果表明:FeCoCrNiZrx合金具有典型的共晶组织,由面心立方固溶体和C15 Laves相组成。随着Zr含量的增加,合金硬度呈先增大后减小的趋势。根据合成的静态滞回曲线可以看出,FeCoCrNiZr0.5合金具有顺磁性和铁磁性的混合型特征,FeCoCrNiZr0.75合金表现为顺磁性,FeCoCrNiZr1合金表现为典型的铁磁性。同时,FeCoCrNiZrx合金在3.5%(质量分数)NaCl溶液中经历活化与钝化转变。当合金中的Zr含量为0.75%(原子分数)时,合金极化电阻具有最大的阻抗电容半径,钝化膜的耐腐蚀能力最强。

    Abstract:

    FeCoCrNiZrx (x=0.5, 0.75, 1) high-entropy alloys with different Zr contents were prepared by vacuum arc melting. The effects of Zr content on the microstructure, magnetic properties, and electrochemical corrosion properties of the alloys were studied. X-ray diffraction, scanning electron microscope, vibration sample magnetometer, and electrochemical workstation were used to study the magnetic property and electrochemical corrosion ability of FeCoCrNiZrx alloys. Results show that FeCoCrNiZrx alloy has typical eutectic structure, consisting of face-centered cubic solid solution and C15 Laves phase. With the increase of Zr content, the hardness of the alloy increases at first and then decreases. However, according to the synthesized static hysteresis curves, FeCoCrNiZr0.5 alloy shows a mixture characteristic of paramagnetism and ferromagnetism, FeCoCrNiZr0.75 alloy has paramagnetic behavior, and FeCoCrNiZr1 alloy has typical ferromagnetism. Meanwhile, the FeCoCrNiZrx alloy undergoes activation-passivation transition in 3.5wt% NaCl solution. When the content of Zr is 0.75at%, the polarization resistance of the alloy has the maximum impedance capacitance radius, and the corrosion resistance of the passive film is the strongest.

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雷声,刘亚峰,李帅,张正彬,胡珊珊,孙旭.FeCoCrNiZr x 高熵合金的磁性和电化学性能[J].稀有金属材料与工程,2021,50(9):3050~3055.[Lei Sheng, Liu Yafeng, Li Shuai, Zhang Zhengbin, Hu Shanshan, Sun Xu. Magnetic and Electrochemical Properties of FeCoCrNiZr x High-Entropy Alloys[J]. Rare Metal Materials and Engineering,2021,50(9):3050~3055.]
DOI:10.12442/j. issn.1002-185X.20210100

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  • 收稿日期:2021-02-01
  • 最后修改日期:2021-03-01
  • 录用日期:2021-03-22
  • 在线发布日期: 2021-09-26
  • 出版日期: 2021-09-24