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非对称界面耦合对LaCoO3/LaMnO3 双层膜性能调控研究
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合肥师范学院 物理与材料工程学院 光电探测科学与技术安徽高校联合重点实验室,安徽 合肥 230601

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光电探测科学与技术安徽高校联合重点实验室开放课题项目(批准号:2020GDTC02)和合肥师范学院2020年度引进高层次人才科研启动基金项目(批准号:2020rcjj09)


Influence of Asymmetric Interface Coupling on Properties of LaCoO3/LaMnO3 Bilayers
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Universities Joint Key Laboratory of Photoelectric Detection Science and Technology in Anhui Province, School of Physics and Materials Engineering, Hefei Normal University, Hefei 230601, China

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Supported by Universities Joint Key Laboratory of Photoelectric Detection Science and Technology in Anhui Province (2020GDTC02); Hefei Normal University High-Level Talents in 2020 (2020rcjj09)

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    摘要:

    通过高分子辅助溶胶凝胶自旋涂沉积法在(100)取向的SrTiO3衬底上制备出LaCoO3/LaMnO3双层膜。在LaMnO3表面生长一层LaCoO3膜后,由于二者结构对称性差异,最终会在膜层界面处形成非对称界面耦合。由于非对称耦合作用,双层膜的铁磁转变温度从单层LaMnO3的262 K下降为200 K。此外,由于界面处Mn-O-Co的双交换作用,与单层LaMnO3薄膜的矫顽场相比,双层膜的矫顽场增大了约500%。研究结果表明,不同结构和性质的薄膜重组为多层膜的基础研究和高性能功能材料的应用提供了一种新的结构设计途径。

    Abstract:

    The LaCoO3/LaMnO3 bilayers epitaxial film grown on (100) SrTiO3 substrates were obtained by a simple polymer assisted sol-gel deposition method. Growing a LaCoO3 layer on the top of LaMnO3 leads to the asymmetric interface coupling at the interface layer due to their difference in strucural symmetry, and reduces the ferromagnetic transition temperature caused by the asymmetric interface coupling effect from 262 K to 200 K. In addition, compared with the coercive field of isolated LaMnO3 film, the coercive field observed in the bilayers is increased by ~500% due to a strong ferromagnetic Mn-O-Co double exchange interaction at the interface. The results demonstrate that the recombination of multilayer films with different properties provides a new way to design functional materials for fundamental studies or demanding applications.

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谢长征,张国伟,余昌永.非对称界面耦合对LaCoO3/LaMnO3 双层膜性能调控研究[J].稀有金属材料与工程,2021,50(9):3039~3042.[Xie Changzheng, Zhang Guowei, Yu Changyong. Influence of Asymmetric Interface Coupling on Properties of LaCoO3/LaMnO3 Bilayers[J]. Rare Metal Materials and Engineering,2021,50(9):3039~3042.]
DOI:10.12442/j. issn.1002-185X.20210152

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  • 收稿日期:2021-02-25
  • 最后修改日期:2021-04-28
  • 录用日期:2021-05-12
  • 在线发布日期: 2021-09-26
  • 出版日期: 2021-09-24