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多级还原制备钛粉的初级还原机制与配镁量作用规律
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东北大学 冶金学院

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国家自然科学基金资助(U1908225,U1702253);中央高校基本科研业务费专项资金资(N182515007,N170908001,N2025004)


The mechanism of primary reduction and the effect of magnesium contentin the preparation of titanium powder by multistage reduction
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    摘要:

    目前,Kroll法仍是金属钛生产的唯一工业化方法,新开发的电解法和金属热还原法均处于研究阶段。本文针对多级还原制备钛粉进行了初级还原阶段还原机制与配镁量作用规律的研究。通过分析及结果验证,提高配镁量可促进反应进行的动力学,有利于TiO2还原程度的提升并抑制镁杂质残留,镁在初级还原过程中多以流体形式包裹在二氧化钛颗粒表面进行传质形成多相微球,钛氧化物则受高温作用发生烧结形成孔隙网络结构的产物形貌。在考虑镁的利用率及实际深度还原产物品质的基础上,实验确定化学计量比为最佳配料比。该配比的初级还原产物氧含量可达16.04wt%,比表面积和中位粒度分别为1.76m2/g和 34.39μm,制备的钛粉O、Mg含量分别为0.274wt%和0.010wt%。

    Abstract:

    At present, the Kroll method is still the only industrialized method for the production of metal titanium, and the newly developed electrolysis method and metal thermal reduction method are both in the research stage. In this paper, the reduction mechanism of the primary reduction stage and the law of the amount of magnesium are studied for the titanium powder prepared by the multi-stage reduction process. Through analysis and result verification, increasing the amount of magnesium can promote the kinetics of the reaction, which is conducive to the improvement of the reduction of TiO2 and inhibits the residual magnesium impurities. Magnesium is mostly wrapped in fluid form on the surface of titanium dioxide particles for mass transfer formation during the primary reduction process Multiphase microspheres and titanium oxide are sintered under high temperature to form the product morphology of the pore network structure. On the basis of considering the utilization of magnesium and the quality of the actual deep reduction product, the stoichiometric ratio is determined by experiments as the best ingredient ratio. The oxygen content of the primary reduction product of this ratio can reach 16.04wt.%, the specific surface area and the median particle size are 1.76m2/g and 34.39μm, respectively, and the O and Mg content of the prepared titanium powder are 0.274wt.% and 0.010wt.%, respectively.

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闫建鹏,豆志河,张廷安,闫基森,周新宇.多级还原制备钛粉的初级还原机制与配镁量作用规律[J].稀有金属材料与工程,2022,51(4):1470~1477.[Yan Jianpeng, douzhihe, Zhang Tingan, Yan Jisen, Zhou xinyu. The mechanism of primary reduction and the effect of magnesium contentin the preparation of titanium powder by multistage reduction[J]. Rare Metal Materials and Engineering,2022,51(4):1470~1477.]
DOI:10.12442/j. issn.1002-185X.20210340

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  • 收稿日期:2021-04-18
  • 最后修改日期:2021-06-17
  • 录用日期:2021-07-09
  • 在线发布日期: 2022-05-05
  • 出版日期: 2022-04-28