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ZrB2增韧Al2O3陶瓷制备工艺及其对复相陶瓷力学性能影响
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辽宁省化学助剂合成与分离重点实验室 营口理工学院 材料科学与工程学院

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TG174.75

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国家重点研发计划(2020YFC1909300)、辽宁省教育厅项目(L2019002)和营口理工学院创新团队项目(TD201901)资助。


Preparation Technology of ZrB2 Toughened Al2O3 Ceramics and Its Effect on the Mechanical Properties of Multiphase Ceramics
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Liaoning Key Laboratory of Chemical Additive Synthesis and Separation,School of Materials Science and Engineering,Yingkou Institute of Technology,Yingkou,115014

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    摘要:

    Al2O3陶瓷因具有很高的强度和耐蚀性受到广泛关注。但由于相对较差的韧性限制了其广泛应用。Al2O3陶瓷增韧的方式很多,本文采用微米ZrB2来增韧氧化铝陶瓷,探讨复相陶瓷烧结工艺,并研究工艺参数对复相陶瓷力学性能及韧性的影响。结果表明:采用单因素法得到两种陶瓷最佳工艺参数分别是纯α-Al2O3陶瓷烧结温度为1500℃,成型压力为450MPa,保温时间为8h,球料比为1/2,保压时间为10min;ZrB2(wt,20%)+α-Al2O3 (wt,80%)复相陶瓷烧结温度为1450℃,成型压力为450MPa,保温时间为8h,球料比为1/2,保压时间为10min。其中成型压力、烧结温度和保温时间对复相陶瓷硬度及致密度影响最大。ZrB2的加入,在降低陶瓷烧结温度的同时,可以将纯α-Al2O3陶瓷的断裂韧性由5.2±0.3MPa.m1/2提高到6.7±0.2MPa.m1/2

    Abstract:

    Al2O3 ceramics have received widespread attention due to their high strength and corrosion resistance. However, its wide application is limited due to its relatively poor toughness. There are many ways to toughen Al2O3 ceramics. This article uses micron ZrB2 to toughen alumina ceramics, discusses the sintering process of composite ceramics, and studies the influence of process parameters on the mechanical properties and toughness of composite ceramics. The results show that the best process parameters of the two ceramics obtained by the single factor method are pure α-Al2O3 ceramic sintering temperature of 1500℃, molding pressure of 450MPa, holding time of 8h, ball-to-battery ratio of 1/2, and holding time of 10min; ZrB2 (wt, 20%)+α-Al2O3 (wt, 80%) multiphase ceramic sintering temperature is 1450℃, molding pressure is 450MPa, holding time is 8h, ball-to-battery ratio is 1/2, and pressure holding time is 10min. Among them, the molding pressure, sintering temperature and holding time have the greatest influence on the hardness and density of the composite ceramics. The addition of ZrB2 can increase the fracture toughness of pureα-Al2O3 ceramics from 5.2±0.3MPa.m1/2 to 6.7±0.2MPa.m1/2 while lowering the ceramic sintering temperature.

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苏阳,王晓民. ZrB2增韧Al2O3陶瓷制备工艺及其对复相陶瓷力学性能影响[J].稀有金属材料与工程,2022,51(5):1857~1863.[Yang Su, Xiao-min Wang. Preparation Technology of ZrB2 Toughened Al2O3 Ceramics and Its Effect on the Mechanical Properties of Multiphase Ceramics[J]. Rare Metal Materials and Engineering,2022,51(5):1857~1863.]
DOI:10.12442/j. issn.1002-185X.20210416

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  • 收稿日期:2021-05-12
  • 最后修改日期:2021-06-04
  • 录用日期:2021-06-22
  • 在线发布日期: 2022-06-09
  • 出版日期: 2022-05-30