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ZrC-HfC-TaC改性C/SiC复合材料的循环氧化烧蚀行为
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航天特种材料及工艺技术研究所,北京 100074

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基金项目:

国家自然科学基金项目(批准号:22102165)


Cyclic Oxidation and Ablation Behavior of ZrC-HfC-TaC Modified C/SiC Composites
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Affiliation:

Aerospace Institute of Advanced Materials and Processing Technology, Beijing 100074, China

Fund Project:

National Natural Science Foundation of China (22102165)

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    摘要:

    难熔金属碳化物改性是提升陶瓷基复合材料抗氧化性能的有效途径。然而,ZrC-HfC-TaC改性对循环氧化烧蚀性能的影响却鲜有报道。利用前驱体浸渍裂解结合化学气相沉积工艺构筑了ZrC-HfC-TaC改性C/SiC复合材料,剖析了1600 ℃/5 h循环静态氧化后材料的力学强度、化学组成以及微观结构的变化,根据表征结果提出了改性后材料的抗氧化机理,并利用1700 ℃/4000 s循环氧乙块焰烧蚀试验验证了ZrC-HfC-TaC改性对提升循环氧化烧蚀性能的有效性。研究表明,经过ZrC-HfC-TaC改性的C/SiC复合材料具备优异的高温循环氧化烧蚀性能。

    Abstract:

    Refractory metal carbides have been widely proven to be an effective strategy to enhance the oxidation resistance of ceramic matrix composites. The modification effect of ZrC-HfC-TaC system on cyclic oxidation and ablation behavior has rarely been explored. Herein, ZrC-HfC-TaC modified C/SiC composites were fabricated by polymer infiltration and pyrolysis and chemical vapor deposition processes. The mechanical strength, chemical composition and microstructure after cyclic static oxidation test under 1600 °C/5 h were investigated, and the corresponding oxidation mechanism was proposed according to the characterization results. The cyclic oxyacetylene torch tests under 1700 °C/4000 s were also employed to verify the effectiveness of ZrC-HfC-TaC modification on C/SiC composites. Results suggest that ZrC-HfC-TaC modified C/SiC composites possess outstanding cyclic oxidation and ablation behavior.

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陈昊然,刘伟,孙娅楠,冯士杰,杨彤,杨良伟,张宝鹏,宋环君,孙同臣.ZrC-HfC-TaC改性C/SiC复合材料的循环氧化烧蚀行为[J].稀有金属材料与工程,2022,51(12):4429~4435.[Chen Haoran, Liu Wei, Sun Yanan, Feng Shijie, Yang Tong, Yang Liangwei, Zhang Baopeng, Song Huanjun, Sun Tongchen. Cyclic Oxidation and Ablation Behavior of ZrC-HfC-TaC Modified C/SiC Composites[J]. Rare Metal Materials and Engineering,2022,51(12):4429~4435.]
DOI:10.12442/j. issn.1002-185X.20220009

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历史
  • 收稿日期:2022-01-05
  • 最后修改日期:2022-12-03
  • 录用日期:2022-03-07
  • 在线发布日期: 2023-01-11
  • 出版日期: 2022-12-30