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钕铁硼磁粉HDDR工艺各向异性生成机理研究
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1.中国石油大学华东 材料科学与工程学院;2.中国石油大学华东 理学院

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山东省自然科学基金(ZR2020ME010);青岛市科技发展计划(22-3-7-cspz-9-nsh)


Anisotropic Properties of NdFeB Magnetic Powder Treated by HDDR Process
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1.China University of PetroleumEast China School of Materials Science and Engineering;2.China University of PetroleumEast China college of science

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    摘要:

    本文对钕铁硼速凝薄带进行“氢化-歧化-脱氢-复合”工艺(HDDR)处理,研究了歧化时间、脱氢压力对HDDR磁粉磁性能的影响及磁各向异性的产生机理。通过XRD对其进行物相表征,SEM观察微观形貌及磁性能测试,结果表明:歧化时间决定了HD工艺后磁粉材料中歧化相和残余母相Nd2Fe14BH1.04的含量,残余母相能够更好地将母相的织构信息传递下去,使得新相Nd2Fe14B有很强的c轴织构,磁粉在歧化时间为40 min时各向异性达到最佳,DOA=0.55。而脱氢压力主要作为晶体生长的驱动力,压力在0.01 MPa时驱动力过大,导致脱氢之后晶粒生长方向随机,c轴织构不明显,生成的新相Nd2Fe14B的各向异性较弱;磁粉在脱氢压力为0.03 Mpa时各向异性得到显著增强,DOA=0.53。

    Abstract:

    Effects of disproportionation time and dehydrogenation pressure on the magnetic properties and anisotropy of HDDR magnetic powders were studied. The phase structures of the samples were identified by X-ray powder diffraction. The microstructure was investigated using scanning electron microscope. The magnetic properties of NdFeB were measured by AMT-4A magnetic measuring instrument. The results showed that the disproportionation time determines the content of the disproportionated phase and the residual parentNd2Fe14BH1.04 phase in the material after the HD process. The residual parent Nd2Fe14BH1.04 can inherit the texture information of the original Nd2Fe14B phase, which results in strong c-axis texture of new phase Nd2Fe14B. When the disproportionation time extends to 40 min, the anisotropy of the magnetic powder reaches the maximum, DOA=0.55. The dehydrogenation pressure mainly acts as the driving force for the crystal growth. The low pressure of 0.01 Mpa will cause over large driving force, which leads to the weak anisotropy of the generated new phase Nd2Fe14B. The magnetic powder has the optimum anisotropy when the dehydrogenation pressure is at 0.03 Mpa, DOA=0.53.

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于濂清,刘科,张亚萍,朱海丰.钕铁硼磁粉HDDR工艺各向异性生成机理研究[J].稀有金属材料与工程,2023,52(11):3867~3872.[Yu Lianqing, Liu Ke, Zhang Yaping, Zhu Haifeng. Anisotropic Properties of NdFeB Magnetic Powder Treated by HDDR Process[J]. Rare Metal Materials and Engineering,2023,52(11):3867~3872.]
DOI:10.12442/j. issn.1002-185X.20220841

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  • 收稿日期:2022-10-26
  • 最后修改日期:2023-02-08
  • 录用日期:2023-02-14
  • 在线发布日期: 2023-11-27
  • 出版日期: 2023-11-22