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TiN薄膜增强改性钛双极板耐蚀性
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西安交通大学金属材料强度国家重点实验室

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国家重点研发计划 (2022YFB4002100)


Enhanced Corrosion resistance of Titanium bipolar plate modified by Titanium Nitride film
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State Key Laboratory for Mechanical Behavior of Materials,Xi’an Jiaotong University,Xi’an

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National Key Research and DevelopmentProgram of China (2022YFB4002100)

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    摘要:

    质子交换膜水电解槽(Proton exchange membrane water electrolyzer, PEMWE)是新一代清洁高效的制氢装置,而双极板是其关键组成部件之一。为了提高钛双极板的耐蚀性,采用磁控反应溅射技术和脉冲沉积技术在商业纯钛 TA1 表面制备了氮化钛(TiN)薄膜,并对不同工艺参数下制备的薄膜进行了评价。结果表明,在不同制备工艺下 Ti表面均可以形成致密完整的TiN膜,并显著提高钛基体的腐蚀电流密度。其中,磁控反应溅射所制备的薄膜成分受到氧气竞争反应的影响,其均一性低于脉冲激光沉积所制备的薄膜,脉冲激光沉积制备的薄膜在低腐蚀电流(0.025μA cm?2)、中等腐蚀过电位(–0.106V)和良好的疏水性方面具有更优异的综合性能。

    Abstract:

    Proton exchange membrane water electrolyzer (PEMWE) is a new generation of clean and efficient hydrogen production device. Bipolar plate is one of its key components. To improve the corrosion resistance of Titanium (Ti) as bipolar plate, Titanium Nitride (TiN) film was prepared on the surface of industrial TA1 by magnetron reactive sputtering (MRS) and pulse laser deposition (PLD) technologies, and the films prepared under different process parameters were evaluated. The results show that dense and complete TiN films can be obtained on Ti surface under different preparation processes, and the corrosion current density of Ti substrate is significantly increased. However, the composition of the film prepared by magnetron reactive sputtering is affected by the oxygen competition reaction, and its homogeneity is inferior to that of the film prepared by pulse laser deposition. The comprehensive performance of the PLD-prepared film is more excellent in terms of low corrosion current (0.025 μA.cm?2), moderate corrosion overpotential (?0.106 V), and good hydrophobicity.

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邓真桢,戴正飞,伍维博,来睿思,王琛,吕源江,马飞. TiN薄膜增强改性钛双极板耐蚀性[J].稀有金属材料与工程,,().[Zhenzhen Deng, Zhengfei Dai, Weibo Wu, Ruisi Lai, Chen Wang, Yuanjiang Lv, Fei Ma. Enhanced Corrosion resistance of Titanium bipolar plate modified by Titanium Nitride film[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-04-02
  • 最后修改日期:2024-07-06
  • 录用日期:2024-07-08
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