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新型Co-Ni-Al-W高温合金中γ′析出相粗化特性及压缩性能的研究
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中国机械总院集团沈阳铸造研究所有限公司

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Natural Science Foundation of Liaoning Province (No. 2023-MSLH-337)


Investigating coarsening characteristics of γ′ precipitates and compression performance in a novel Co-Ni-Al-W superalloy
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Natural Science Foundation of Liaoning Province (No. 2023-MSLH-337)

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    摘要:

    本文深入研究了新型Co-Ni-Al-W高温合金在不同时效温度下γ′相的粗化行为及压缩性能。实验结果表明,γ′相的平均半径和体积分数演化遵循经典的Lifshitz-Slyozov-Wagner (LSW)模型。随着时效温度的提升,γ′相的粗化速率显著增大,从800℃的1.30×10-27 m3/s增长至900℃的9.56×10-27 m3/s。研究发现,γ′相的粗化活化能为210 kJ/mol,这主要受到W元素在γ基体中的扩散过程所控制。Co-Ni-Al-W合金展现出高γ′溶质温度(1221℃)和低密度(8.7 g/cm3)的优异特性。此外,该合金在常温和高温条件下的压缩屈服强度超越了近年来发展的典型γ′强化Co基高温合金,显示出其卓越的性能和应用前景。

    Abstract:

    In the present study, the coarsening behavior of γ? phase at different temperatures and the compression property of a novel Co–Ni–Al–W superalloy was investigated. The evolution of the mean radius and volume fraction of the γ? phase indicates that the coarsening behavior follows the classical Lifshitz-Slyozov-Wagner (LSW) model. The coarsening rate of the γ" phase exhibits a significant dependence on the aging temperature, increasing from 1.30×10-27 m3/s at 800 ℃ to 9.56×10-27 m3/s at 900 ℃. The activation energy of γ? phase, influenced mainly by W diffusion in the γ matrix, is found to be 210 kJ/mol. In particular, the studied Co-Ni-Al-W alloy possesses a good combination of a high γ? solvus temperature of 1221 ℃ and a low density of 8.7 g/cm3. Besides, compression yield strength of the developed Co-Ni-Al-W alloy at ambient and high temperatures are higher than those of other recently γ?-strengthened Co-based superalloys.

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周成,金磊,荆高扬,于伯岩,赵军.新型Co-Ni-Al-W高温合金中γ′析出相粗化特性及压缩性能的研究[J].稀有金属材料与工程,,().[Cheng Zhou, Lei Jin, Gaoyang Jing, Boyan Yu, Jun Zhao. Investigating coarsening characteristics of γ′ precipitates and compression performance in a novel Co-Ni-Al-W superalloy[J]. Rare Metal Materials and Engineering,,().]
DOI:10.12442/j. issn.1002-185X.20240244

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  • 收稿日期:2024-04-25
  • 最后修改日期:2024-06-05
  • 录用日期:2024-06-07
  • 在线发布日期: 2024-06-17
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