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Cu对高强6000系铝合金峰时效析出相和性能的影响
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中国有研科技集团有限公司 有色金属材料制备加工国家重点实验室

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国家重点研发计划(项目号No. 2023YFB3710402)


Effect of Cu on microstructure and intergranular corrosion properties of high strength 6000 series aluminum alloy
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State Key Laboratory of Non-Ferrous Metals and Processes,GRINM Group Co,Ltd

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    摘要:

    通过OM、TEM、HRTEM、室温拉伸和晶间腐蚀实验研究了Cu对高强6000系铝合金峰时效态析出相、拉伸性能和晶间腐蚀性能的影响。结果表明,添加Cu促进了合金峰时效态析出相的析出,随着Cu含量从0增加到0.18wt.%和0.37wt.%,峰时效态合金的析出相尺寸明显减小,体积分数从4.05%提升到4.61%和5.36%,对应合金的强度从421MPa提高到448MPa和459MPa;结合HRTEM发现三种合金峰时效态的主要析出相为β″相,其中添加0.37wt.% Cu的合金中还发现了L相。添加0.18wt.% Cu对合金的耐晶间腐蚀性能有改善作用,而0.37wt.% Cu的添加则降低了合金的耐晶间腐蚀性能。通过对合金晶内及晶界析出相的研究,发现0.18wt.% Cu的添加促进了晶内强化β″相的析出,细化了晶界处无沉淀析出带(PFZ)的宽度,PFZ宽度为51.92nm;0.37wt.% Cu的添加促进了强化相的析出,同时改变了析出相类型,此外还发现0.37wt.% Cu的添加显著粗化了晶界处无沉淀析出带的宽度,PFZ宽度为60.20 nm。结合时效析出相、拉伸强度和晶间腐蚀性能,发现0.18wt.%Cu合金具有优良的综合性能。

    Abstract:

    The effect of Cu on the peak aging precipitates, tensile properties and intergranular corrosion properties of 6000 series aluminum alloy were investigated by OM, TEM, HRTEM, tensile and intergranular corrosion test. The results shown that the addition of Cu promoted the precipitation of the peak aging phase of the alloy. With the Cu content increasing from 0 to 0.18wt.% and 0.37wt.%, the precipitates size of the peak aging alloy decreased significantly, and the volume fraction increases from 4.05% to 4.61% and 5.36%. The strength of the corresponding alloys increased from 421MPa to 448 MPa and 459MPa. According to HRTEM, the main precipitates of the three alloys in peak aging state was β "phase, and L phase was also found in the alloy with 0.37 wt.% Cu added. The addition of 0.18 wt.% Cu improved the intergranular corrosion resistance of the alloy, while the addition of 0.37 wt.% Cu decreased the intergranular corrosion resistance of the alloy. It was found that the addition of 0.18 wt.% Cu promoted the precipitation of β "phase in the alloy, and the width of the precipitation free zone (PFZ) at the grain boundary was refined to 51.92nm. The addition of 0.37 wt.% Cu promoted the precipitation of the strengthened phase and changed the type of the precipitated phase. In addition, it was found that the addition of 0.37 wt.% Cu significantly roughened the width of the PFZ at the grain boundary, and the PFZ width was 60.20nm. Combined with aging precipitates, tensile strength and intergranular corrosion, it is found that 0.18wt.%Cu alloy has excellent comprehensive properties.

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张旭,闫丽珍,李志辉,李锡武,高冠军,张永安,刘红伟,熊柏青. Cu对高强6000系铝合金峰时效析出相和性能的影响[J].稀有金属材料与工程,,().[Zhang Xu, Yan Lizhen, Li Zhihui, Li Xiwu, Gao Guanjun, Zhang Yongan, Liu Hongwei, Xiong Baiqing. Effect of Cu on microstructure and intergranular corrosion properties of high strength 6000 series aluminum alloy[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-05-17
  • 最后修改日期:2024-10-29
  • 录用日期:2024-11-08
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