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Cu对热轧Mg-3Zn-1Y合金组织和腐蚀行为的影响
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太原科技大学

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山西省基础研究计划 ( 202203021222188 、 202303021211166), 中央引导地方科技发展基金 (YDZJSK20231A046), 山西省重点研究项目 ( 202102050201003 、202203D111001).


Effects of Cu on the microstructure and corro-sion behaviour of hot-rolled Mg-3Zn-1Y alloys
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Fundamental Research Program of Shanxi Province (Grant No. 202203021222188 and 202303021211166), the Central Guiding Science and Technology Development of Local Fund (Grant No. YDZJSK20231A046), and the Key Scientific Re-search Project in Shanxi Province (Grant No. 202102050201003 and 202203D111001).

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    摘要:

    本文研究了热轧Mg-3Zn-1Y-xCu合金(x = 0, 1, 3, 5 wt%)的微观组织和腐蚀行为。Mg-3Zn-1Y-xCu合金都包含了α-Mg和Mg3Zn6Y相。添加Cu元素后,合金出现了MgZnCu相,并且MgZnCu相的数量随着Cu的量增加而增加。电化学和浸泡试验结果表明添加Cu后Mg-3Zn-1Y-xCu合金的耐蚀性能下降。这加速的耐腐蚀速率受到了合金微观组织和腐蚀产物膜性能的影响。具有高电化学电势的MgZnCu相作为强阴极加速了微电偶腐蚀。腐蚀产物膜防护性能的下降源于相应化合物PBR值的改变。

    Abstract:

    The microstructure and corrosion behaviour of hot-rolled Mg-3Zn-1Y-xCu alloys (x = 0, 1, 3, 5 wt%) were investigated. All alloys mainly consisted of α-Mg matrix and Mg3Zn6Y particles. The addition of Cu formed MgZnCu phase, and the amount of MgZnCu phase increased with the increasing Cu content. The deteriorated corrosion resistance of Mg-3Zn-1Y-xCu alloys with Cu addition had been proved by the electrochemical and immersion results, which can be attributed to the in?uence of the microstructure of alloys and properties of the formed corrosion products ?lm in the corrosion media. The formed MgZnCu particles with high electrochemical potential as strong cathodic sites accelerate the micro-galvanic corrosion and degraded the protectiveness of the corrosion product ?lm resulting from changed PBR of related compounds.

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张跃忠,陈小亭,沈静,武鹏鹏,张少华,刘宝胜. Cu对热轧Mg-3Zn-1Y合金组织和腐蚀行为的影响[J].稀有金属材料与工程,,().[Zhang Yuezhong, Chen xiaotin, Shen jing, Wu pengpeng, Zhang Shaohua, Liu Baosheng. Effects of Cu on the microstructure and corro-sion behaviour of hot-rolled Mg-3Zn-1Y alloys[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-05-17
  • 最后修改日期:2024-06-07
  • 录用日期:2024-06-14
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