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铝合金表面超声/激光复合原位合金化Ti-B4C涂层的组织及性能研究
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1.浙江工业大学激光先进制造研究院;2.江苏丰东热技术有限公司

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国家自然科学基金(52205221);浙江省自然科学基金(Y24E050091);中国博士后科学基金(2023M741445);省属高校基本科研业务费项目(RF-A2023008)


Microstructure and properties of ultrasonic/laser hybrid in-situ alloying Ti-B4C coatings on aluminum surfaces
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    摘要:

    以Ti-B4C为合金化材料,采用超声振动辅助激光合金化工艺在7075铝合金表面原位制备了多元陶瓷颗粒增强铝基复合涂层。研究了不同超声波振幅(0 μm、50 μm、70 μm和90 μm)对涂层整体形貌、相组成、微观结构、显微硬度与耐磨性能的影响,分析了超声振动对激光合金化过程中原位增强相尺寸、形态、空间分布等的作用机制。结果表明,在激光合金化过程中辅助超声波振动并未改变涂层的物相组成,但促进了熔池中原位化学反应的进行,原位生成陶瓷增强相如TiB2、TiC等的衍射峰随着超声振幅的增加而增强。引入超声振动后,强烈的熔池对流使得涂层表面形貌得到改善,粗糙度略有增加,涂层厚度和稀释率提高。随着超声振幅的增加,声空化效应和声流效应增强,涂层微观组织显著细化,原位生成增强颗粒的数量增加、空间分布更加均匀。其中原位生成的TiB2、TiC与α-Al之间界面结合良好,界面失配率分别约为5.83 %和6.81 %,表明其可作为有效形核质点促进晶粒细化。引入超声振动后,涂层的显微硬度显著提高且分布更加均匀,当超声振幅为70 μm时,涂层平均显微硬度约为703.87 HV0.2,是基体和未施加超声时涂层硬度5.76和1.66倍。此时,涂层的耐磨性最佳,磨损机理仅为轻微磨料磨损,耐磨性约为基材的11.8倍,是无超声辅助涂层的4.1倍。

    Abstract:

    Using Ti-B4C as the alloying material, an in-situ various ceramic particles reinforced aluminum matrix composite coating was prepared on the surface of 7075 aluminum alloy using ultrasonic vibration assisted laser alloying process. The effects of different ultrasonic amplitudes (0 μm, 50 μm, 70 μm and 90 μm) on the overall morphology, phase composition, microstructure, microhardness and wear resistance of the coatings were investigated. The mechanism of ultrasonic vibration on the size, morphology and spatial distribution of in-situ reinforcement phases in the laser alloying process was analyzed. The results showed that assisted ultrasonic vibration during laser alloying did not change the phase composition of the coatings, but promoted the in-situ chemical reactions in the melt pool. The diffraction peaks of in-situ synthesized ceramics reinforcement phases such as TiB2 and TiC were increased with the rise of ultrasonic amplitude. The strong convection in the melt pool produced by the ultrasonic vibrations resulted in an improvement of the coating surface macro-morphology, a slight increase in roughness, and an increase in coating thickness and dilution. With the increase of ultrasound amplitude, the acoustic cavitation effect and the acoustic flow effect are enhanced, and the microstructure of the coating is significantly refined. The in-situ synthesized reinforcement particles were not only increased in number but also more uniformly spatially distributed. Both in-situ synthesized TiB2 and TiC were well bonded to the interface between α-Al, with interfacial mismatch rates of about 5.83 % and 6.81 %, respectively, suggesting that they can act as effective nucleation sites to promote grain refinement. The microhardness of the coatings was significantly increased and more uniformly distributed after assisted ultrasonic vibration. The average microhardness of the coatings at an ultrasonic amplitude of 70 μm was about 703.87 HV0.2, which was 5.76 and 1.66 times higher than the hardness of the coatings in the substrate and without ultrasonic vibration. At this time, the coating has the optimum wear resistance, and the wear mechanism is only slight abrasive wear. The wear resistance was approximately 11.8 times that of the substrate, and 4.1 times that of the coating without ultrasonic vibration.

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迟一鸣,钱大虎,郑彪,姚喆赫,韩伯群,姚建华.铝合金表面超声/激光复合原位合金化Ti-B4C涂层的组织及性能研究[J].稀有金属材料与工程,,().[Chi Yiming, Qian Dahu, Zhe Biao, Yao Zhehe, Han Boqun, Yao Jianhua. Microstructure and properties of ultrasonic/laser hybrid in-situ alloying Ti-B4C coatings on aluminum surfaces[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-05-22
  • 最后修改日期:2024-07-04
  • 录用日期:2024-07-10
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