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Zr2Cu封填改性对PIP制备的C/C-SiC-ZrC复合材料微观结构和性能的影响
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1.长安大学;2.西安鑫垚陶瓷复合材料股份有限公司;3.火箭军工程大学

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Effects of Zr2Cu packing modification on the microstructure, mechanical and ablation properties of PIP C/C-SiC-ZrC composites
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    摘要:

    为了改善聚合物浸渍裂解法(PIP)制备的C/C-SiC-ZrC复合材料的致密度和性能,以Zr2Cu为填料,采用低温反应熔体浸渍工艺(RMI)对复合材料进行封孔,研究了Zr2Cu 封填后复合材料的微观结构、力学性能和烧蚀性能。结果表明:在Zr2Cu浸渍过程中,熔体有效地填充了复合材料的大孔隙,并且由于部分锆与碳发生化学反应,Zr2Cu转化为ZrCu。材料的密度从1.91 g/cm3增加至2.24 g/cm3,孔隙率降低了27.35%。此外,封填后的C/C-SiC-ZrC复合材料的弯曲强度从 122.78±8.09 MPa提高至 135.53±5.40 MPa,等离子体烧蚀 20 s,较PIP C/C-SiC-ZrC相比,表现出更优越的耐烧蚀性,其质量烧蚀率和线性烧蚀率分别为 2.77×10-3 g/s 和 2.60×10-3 mm/s。低熔点含铜相的“自蒸发”效应吸收了等离子火焰的热量,进一步降低了烧蚀温度,促进了SiO2熔化层内细化ZrO2颗粒的形成,这为Zr2Cu封填C/C-SiC-ZrC复合材料提供了更稳定的侵蚀保护。

    Abstract:

    In order to improve the compactness and properties of C/C-SiC-ZrC composites produced by precursor infiltration and pyrolysis (PIP) method, the low-temperature reactive melt infiltration process (RMI) was used to seal the composites using Zr2Cu as the filler. The microstructure, mechanical properties and ablation properties of the Zr2Cu packed composites were analyzed. During Zr2Cu impregnation, the melt efficiently filled the large pores of the composites and converted to ZrCu due to a partial reaction of zirconium with carbon. This resulted in an increased composite density of 2.24 g/cm3 and a 27.35% reduction in open porosity. Additionally, the flexural strength of Zr2Cu packed C/C-SiC-ZrC composites improved from 122.78±8.09 MPa to 135.53±5.40 MPa. After plasma ablation for 20 s, the modified composites demonstrated superior ablative resistance compared to PIP C/C-SiC-ZrC, with mass ablation and linear ablation rates of 2.77×10-3 g/s and 2.60×10-3 mm/s, respectively. The “self-transpiration” effect of the low melting point copper-containing phase absorbed the heat of the plasma flame, further reducing the ablation temperature and promoting the formation of refined ZrO2 particles within the SiO2 melting layer. This provided more stable erosion protection for Zr2Cu packed C/C-SiC-ZrC composites.

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解静,张前,任静,苏海龙,田录,支雄辉,孙国栋,李辉,王龙. Zr2Cu封填改性对PIP制备的C/C-SiC-ZrC复合材料微观结构和性能的影响[J].稀有金属材料与工程,,().[Xie Jing, Zhang Qian, Ren Jing, Su Hailong, Tian Lu, Zhi Xionghui, Sun Guodong, Li Hui, Wang Long. Effects of Zr2Cu packing modification on the microstructure, mechanical and ablation properties of PIP C/C-SiC-ZrC composites[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-07-04
  • 最后修改日期:2024-11-25
  • 录用日期:2024-12-03
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