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Zr/CoCrFeMnNi HEA钎焊接头界面组织与力学性能研究
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1.哈尔滨工业大学 材料结构精密焊接与连接全国重点实验室;2.郑州机械研究所有限公司

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TG454

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国家自然科学基金(52275321,52205348),山东省自然科学基金(ZR2023JQ021),浙江省“尖兵”“领雁”研发攻关 计划项目(2024C01086)


Interfacial microstructure and mechanical properties of Zr/CoCrFeMnNi HEA brazed joints
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1.State Key Laboratory of Precision Welding &2.Joining of Materials and Structures,Harbin Institute of Technology;3.State Key Laboratory of Advanced Brazing Filler Metals and Technology,Zhengzhou Research Institute of Mechanical Engineering Co,Ltd;4.State Key Laboratory of Precision Welding &

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    摘要:

    采用AgCu钎料实现了Zr合金与CoCrFeMnNi HEA之间的钎焊连接。研究了钎焊温度与保温时间对接头显微组织演化规律与力学性能的影响规律。结果表明:在钎焊温度为850 ℃,保温时间为10 min的条件下,接头界面的典型微观组织为:HEA/Crss/Zr(Cr,Mn)2/Zr2(Co,Cu,Ni,Fe)+Zr2(Ag,Cu)+Zr(Cr,Mn2/Zr,接头的平均剪切强度最高可达103.1 MPa。随着钎焊温度的升高或保温时间的增加,扩散反应区内的富Cr基固溶体层和Zr(Cr,Mn)2层厚度增厚,钎缝中心区内Zr2(Co,Cu,Ni,Fe)相和Zr(Cr,Mn)2相含量增多,Zr2(Ag,Cu)相所占比例减小。最后,分析了接头的失效机制,在剪切力的作用下,随着钎焊温度和保温时间的增加,接头的断裂位置从扩散反应区的Zr(Cr,Mn)2层转移到钎缝中心区的Zr2(Co,Cu,Ni,Fe)脆性相断裂。

    Abstract:

    AgCu filler was used to obtain the brazing between Zr and CoCrFeMnNi HEA. The effects of brazing temperature and holding time on the microstructure and mechanical properties of the joints were analyzed. The results displayed that the typical microstructure of the joints brazed at 950 ℃ for 10 min was HEA/Crss/Zr(Cr,Mn)2/Zr2(Co,Cu,Ni,Fe)+Zr2(Ag,Cu)+Zr(Cr,Mn)2/Zr.The Joints had the maximum shear strength of 103.1 MPa. As the brazing temperature or holding time raised, the thickness of Cr-rich solid solution and Zr(Cr,Mn)2 layer were increased, the content of Zr2(Co,Cu,Ni,Fe) and Zr(Cr,Mn)2phase were increased whereas Zr2(Ag,Cu) phase was decreased. Finally, the failure mechanism of the joint was analyzed. Under the action of shear force, as the brazing temperature or holding time raised, the fracture position of the joint shifted from the Zr(Cr,Mn)2layer to the Zr2(Co,Cu,Ni,Fe) phase fracture in the center of the brazing seam.

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杜鹏,宋晓国,龙伟民,卞红,秦建,孙华为,姜楠. Zr/CoCrFeMnNi HEA钎焊接头界面组织与力学性能研究[J].稀有金属材料与工程,,().[Du Peng, Song Xiaoguo, Long Weimin, Bian Hong, Qin Jian, Sun Huawei, Jiang Nan. Interfacial microstructure and mechanical properties of Zr/CoCrFeMnNi HEA brazed joints[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-09-11
  • 最后修改日期:2024-12-11
  • 录用日期:2024-12-11
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