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电参数调控TC4微弧氧化膜层耐蚀性的研究
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兰州理工大学 材料科学与工程学院

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TG174.4

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甘肃省科技重大专项资助(项目号22ZD6GA008);甘肃省科技计划资助——科技专员专项(项目号24CXGA045)


Study of Electric Parameters to regulate Corrosion Resistance of MAO Coating on TC4
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Gansu Provincial Science and Technology Major Project;Gansu Provincial Science and Technology Programme Funding - Commissioner for Science and Technology Special Project

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    摘要:

    本文采用极差分析法研究电压、脉冲频率、占空比和处理时间的共同作用对TC4钛合金微弧氧化膜层耐蚀性的影响,进而探寻影响膜层耐蚀性的电参数显著性关系和最佳因素水平组合。同时结合膜层形貌和物相组成进一步探讨电参数对膜层耐蚀性的影响机制并建立回归方程,以此来实现通过电参数对微弧氧化膜层耐蚀性的调控。结果表明:占空比对膜层电化学耐蚀性影响的显著性最高,其次是脉冲频率和电压,处理时间对其影响较小。占空比和脉冲频率通过改变燃弧放电时间和熄弧冷却时间来影响膜层结构和性能,增加电压、占空比、处理时间或降低脉冲频率可使电源输出功率增加,导致膜层厚度增加、微孔孔径增大、致密度降低,膜层中Al2TiO5的生成效率更高,电化学耐蚀性能随之降低。通过相关系数法检验可知:所建立回归方程的因变量与自变量之间具有高度相关性,可以为钛合金微弧氧化膜的性能调控提供理论支持和预测方法。

    Abstract:

    This paper investigates the effects of voltage, pulse frequency, duty cycle and processing time on the corrosion resistance of micro-arc oxidised TC4 titanium alloy coatings using polar analysis of variance (ANOVA), with a subsequent objective of exploring the significance relationship and the optimum combination of the factor levels of the electrical parameters. Concurrently, an investigation was conducted into the mechanisms through which electrical parameters influence the corrosion resistance of the film layer, with a particular focus on its morphology and physical composition. A regression equation is established to facilitate regulation of the corrosion resistance properties of micro-arc oxidized films through manipulation of electrical parameters. The findings indicate that the duty cycle exerts the most significant influence on the electrochemical corrosion resistance of the membrane layer, the next most influential factors are pulse frequency and voltage, processing time was observed to have a comparatively lesser effect. The duty cycle and pulse frequency influence both structure and performance characteristics of the film layer by altering arc ignition discharge duration as well as arc quenching cooling times. An increase in voltage, duty cycle, processing time, or a decrease in pulse frequency can result in an enhanced power output from the power supply, this leads to an increase in film thickness along with larger pore sizes within microporous structures while reducing densification. Additionally, it promotes more efficient generation of Al2TiO5 within the film layer, however, this ultimately results in diminished electrochemical corrosion resistance. The results of the correlation coefficient testing demonstrate a strong relationship between the dependent and independent variables within the established regression equation. This finding provides theoretical support for predicting methods aimed at regulating performance characteristics in titanium alloy micro-arc oxidation films.

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王晟,张亚利,刘昊明,刘昱畅,王浩旭,马颖,李元东.电参数调控TC4微弧氧化膜层耐蚀性的研究[J].稀有金属材料与工程,,().[Wang Sheng, Zhang Yali, Liu Haoming, Liu Yuchang, Wang Haoxu, Ma Ying, Li Yuandong. Study of Electric Parameters to regulate Corrosion Resistance of MAO Coating on TC4[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-09-19
  • 最后修改日期:2024-11-18
  • 录用日期:2024-11-18
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