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Ag-Cu-In-Ti低温钎料真空钎焊金刚石/铜接头的界面组织和力学性能研究
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作者单位:

1.浙江工业大学机械工程学院;2.中国能源建设集团浙江火电建设有限公司;3.中国机械总院集团郑州机械研究所有限公司,新型钎焊材料与技术国家重点实验室;4.安徽工程大学材料科学与工程学院;5.华北水利水电大学河南省高效特种绿色焊接国际联合实验室;6.浙江亚通新材料股份有限公司

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基金项目:

国家重点研发计划资助项目(2021YFB3401100);国家自然科学基金(52261044);泰山产业领军人才工程专项经费资助(2024001).


Interfacial Structure and Mechanical Performance of Diamond/Copper Joint Brazed Using Ag-Cu-In-Ti Low-temperature Brazing Filler Alloy
Author:
Affiliation:

1.College of Mechanical Engineering,Zhejiang University of Technology;2.China Energy Engineering Group Zhejiang Thermal Power Construction Co,Ltd;3.China Academy of Machinery Zhengzhou Research Institute of Mechanical Engineering Co,Ltd

Fund Project:

National Key Research and Development Program of China,National MCF Energy R&D Program (2019YFE03100400)

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    摘要:

    金刚石/铜部件是可控核聚变微波窗口的理想选择。然而,由于金刚石润湿性差以及在高温下容易石墨化,钎焊金刚石面临诸多难题。本研究使用Ag-Cu-In-Ti低温钎料钎焊连接金刚石和铜,系统研究了钎焊温度和保温时间对接头显微组织与力学性能的影响,澄清了接头形成机制并构建了接头组织与力学性能间的关联。结果表明:在钎料中加入适量的In显著降低了钎料的熔点,增强了钎料对金刚石的润湿能力。当钎焊温度为750 °C,保温10 min下,获得了具有良好的冶金结合性能且均匀致密的钎缝组织,接头平均抗剪强度达到了 322 MPa。较低的钎焊温度避免了金刚石石墨化风险,同时也降低了焊接残余应力。本论文开展的研究为聚变堆金刚石微波窗的高性能制造提供了基础理论和技术指导。

    Abstract:

    Diamond/Cu components are ideal choices for controlled nuclear fusion microwave windows. However, diamond brazing poses numerous challenges due to its poor wettability and susceptibility to graphitization at high temperatures. In this work, Ag-Cu-In-Ti low-temperature filler alloy was used to braze the diamond and copper, and the effect of brazing temperature and soaking time on the microstructure and mechanical properties of the joints were investigated systematically. In addition, the joint formation mechanism was clarified, and the correlation between joint microstructure and mechanical performance was established. The results showed that adding an appropriate amount of In into the filler significantly reduced its melting point and enhanced the wettability of the filler toward the diamond. When brazed at 750 °C for 10 min, a uniformly dense braze seam with excellent metallurgical bonding was obtained, achieving an average joint shear strength of 322 MPa. The lower brazing temperature applied mitigated the risk of diamond graphitization and also reduced the residual stresses during joining. The findings obtained provide fundamental theoretical and technical guidance for the high-performance manufacturing of diamond microwave windows in fusion reactors.

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潘昱帆,梁佳斌,聂嘉龙,刘鑫,孙华为,常云峰,李华鑫,闾川阳,徐东,王星星,杨洋,杨建国,贺艳明. Ag-Cu-In-Ti低温钎料真空钎焊金刚石/铜接头的界面组织和力学性能研究[J].稀有金属材料与工程,,().[Yufan Pan, Jiabin Liang, Jialong Nie, Xin Liu, Huawei Sun, Yunfeng Chang, Huaxin Li, Chuanyang Lu, Dong Xu, Xingxing Wang, Yang Yang, Jianguo Yang, Yanming He. Interfacial Structure and Mechanical Performance of Diamond/Copper Joint Brazed Using Ag-Cu-In-Ti Low-temperature Brazing Filler Alloy[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-10-10
  • 最后修改日期:2024-11-21
  • 录用日期:2024-12-02
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