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热处理对含锰β型γ-TiAl合金组织和力学性能的影响
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1.东北大学 材料科学与工程学院 沈阳;2.季华实验室 佛山

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中图分类号:

TG146.23

基金项目:

广东省基础与应用基础研究基金区域联合(地区培育项目)(2023A1515140056);国家自然科学基金(52271026和52471033)


Effect of Heat Treatment on the Microstructure and Mechanical Properties of Mn-Containing β-solidifying γ-TiAl Alloy
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Affiliation:

1.School of Materials Science and Engineering,Northeastern University;2.Ji Hua Laboratory

Fund Project:

Guangdong Province Basic and Applied Basic Research Fund Regional Joint (Regional Cultivation Project)(2023A1515140056);National Natural Science Foundation of China (52271026 and 52471033)

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    摘要:

    β型γ-TiAl合金由于不发生包晶转变,成分偏析小,表现出良好的热加工性和高温性能。Mn作为一种低成本的强β相稳定元素,对发展低成本、易变形的β型γ-TiAl合金发挥着重要作用。本文以一种低成本、易变形的Ti-44Al-3Mn-0.4Mo-0.4W-0.1B-0.1C合金(at.%)为研究对象,利用真空感应熔炼及常规热轧工艺制备了直径为12 mm的棒材,采用电子探针(EPMA)、透射电子显微镜(TEM)、电子背散射衍射(EBSD)等检测手段,研究了1270 ℃、1220 ℃、1170 ℃高温处理对合金棒材的组织与力学性能的影响规律。结果表明,热处理后合金的显微组织均由γ、α2、βo三相组成。在相同时效制度条件下,随着高温处理温度的降低,合金中α2/γ片层含量明显减少,且片层晶团尺寸和片层间距显著降低。拉伸性能测试表明,随着高温处理温度的下降,三种组织的室温和800 ℃拉伸强度均降低。室温条件下,三种热处理延伸率呈现先增加后降低的趋势,数值均处于0.5~1.0%范围;800 ℃条件下,三种热处理延伸率存在明显差异,随着等轴γ相含量的增加,合金延伸率随之增加。对比1270 ℃高温处理,1220 ℃热处理试样的延伸率提高了280%,1170 ℃热处理后提高了480%。这是由于相较室温拉伸,在高温拉伸时,等轴γ相的变形能力大大增强,βo相内位错开动较多,并且γ/γ和α2/γ界面会阻碍孪晶和位错的运动。论文还对不同热处理组织演变行为与规律、组织与力学性能关系进行了深入讨论。

    Abstract:

    Due to the absence of peritectic transformation, β-solidifying γ-TiAl alloys exhibit minimal compositional segregation, thereby demonstrating outstanding thermomechanical processing capabilities and high-temperature performance. Manganese, serving as a cost-effective and potent stabilizer of the β-phase, plays a pivotal role in the development of economically viable and easily deformable β-solidifying γ-TiAl alloys. In this investigation, we focused on a low-cost and easily deformable Ti-44Al-3Mn-0.4Mo-0.4W-0.1B-0.1C alloy (at.%), which was rolled into 12 mm diameter bars via vacuum induction melting and conventional hot rolling techniques. Various characterization methods, including electron probe microanalysis (EPMA), transmission electron microscopy (TEM), and electron backscatter diffraction (EBSD), were employed to scrutinize the effects of high-temperature treatments at 1270 °C, 1220 °C, and 1170 °C on the microstructure and mechanical properties of the alloy bars. The findings reveal that post-heat treatment, the microstructure of the alloy comprises γ, α2, and βo phases. Decreasing the high-temperature treatment temperature under identical aging conditions significantly reduces the α2/γ lamellar content within the alloy. Moreover, both the size of the lamellar colonies and the spacing between lamellae exhibit pronounced reductions as the treatment temperature decreases. The tensile performance tests demonstrate that as the high-temperature treatment temperature decreases, both the room temperature and 800 °C tensile strength of the three microstructures decline. At room temperature, the elongation of the heat-treated microstructures shows a trend of first increasing and then decreasing, with the values all within the range of 0.5% to 1.0%. However, at 800 °C, significant variations in elongation are observed among the microstructures. Specifically, an increase in equiaxed γ phase content correlates with enhanced alloy elongation. Compared to samples treated at 1270 °C, those treated at 1220 °C exhibit a 280% increase in elongation, while those treated at 1170 °C show a 480% increase. This enhancement is attributed to the improved deformability of the equiaxed γ phase at elevated temperatures. Additionally, greater activation of dislocations within the βo phase occurs, while the γ/γ and α2/γ interfaces impede the movement of twins and dislocations. The study further provides a comprehensive discussion on the evolution behavior and patterns of different heat-treated microstructures, emphasizing their correlation with mechanical properties.

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陈传毅,郝俊杰,舒 磊,陈 波,牛红志,李小兵,刘 奎.热处理对含锰β型γ-TiAl合金组织和力学性能的影响[J].稀有金属材料与工程,,().[Chen Chuanyi, Hao Junjie, Shu Lei, Chen Bo, Niu Hongzhi, Li Xiaobing, Liu Kui. Effect of Heat Treatment on the Microstructure and Mechanical Properties of Mn-Containing β-solidifying γ-TiAl Alloy[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-12-03
  • 最后修改日期:2025-02-08
  • 录用日期:2025-02-19
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