+高级检索
低温热熔ZrTiNi含能材料组织性能研究
DOI:
作者:
作者单位:

中国兵器科学研究院宁波分院

作者简介:

通讯作者:

中图分类号:

基金项目:

冲击环境材料技术重点实验室基金


Microstructure and properties of low-temperature hot-melt ZrTiNi energetic materials
Author:
Affiliation:

China Ordnance Science Research Institute Ningbo Branch

Fund Project:

Fund of Key Laboratory of Shock Environment Materials Technology

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    ZrTiNi体系具有独特的低温热熔特性以及较高的化学反应潜能,在战斗部含能壳体中具备潜在应用前景。本文基于三元相图计算对ZrTiNi的低温液相区进行了初步探索,采用真空烧结工艺制备了不同Zr含量(70wt%、80wt%、90wt%)的ZrTiNi合金块体,并对材料的微观组织、物相组成、准静态力学特性以及冲击引发反应特性进行了研究。根据三元相图计算结果,ZrTiNi体系在900℃、950℃以及1000℃下均具有广阔的液相区,展现出显著的低温热熔特性。致密度及金相检测结果显示,950℃烧结得到的Zr70Ti15Ni15、Zr80Ti10Ni10合金样品基本实现完全致密,而Zr90Ti5Ni5合金样品致密度仅81.7%,合金截面仍存在大量孔洞缺陷,这表明随Zr含量增高,合金整体熔点上升。XRD及SEM分析结果显示,ZrTiNi合金均由Zr(Ti)固溶体主相以及Ni-Zr(Ti)金属间化合物组成,并且,Zr含量的增加促进了富Zr固溶体相的形成,对金属间化合物的形成起到一定抑制作用。准静态压缩实验结果表明,致密的Zr70Ti15Ni15、Zr80Ti10Ni10合金样品抗压强度均超过1200MPa,为抗爆轰加载及侵彻穿甲提供了基础条件。在弹道枪实验中,Zr80Ti10Ni10合金弹丸以1029m/s的速度成功击穿前置钢板,并实现航空煤油的持续引燃,表明其具备优异的冲击引发纵火性能。

    Abstract:

    The ZrTiNi system exhibits unique low-temperature melting characteristics and high chemical reactivity potential, offering promising applications in energetic warhead casings. This paper presents a preliminary exploration of the low-temperature liquid phase region of ZrTiNi based on ternary phase diagram calculations. ZrTiNi alloy bulk samples with varying Zr contents (70wt%, 80wt%, and 90wt%) were prepared using a vacuum sintering process, and the materials" microstructure, phase composition, quasi-static mechanical properties, and impact-induced reaction characteristics were studied. According to the phase diagram calculations, the ZrTiNi system has a wide liquid phase region at 900°C, 950°C, and 1000°C, demonstrating significant low-temperature melting characteristics. Relative density and metallographic analysis results show that the Zr70Ti15Ni15 and Zr80Ti10Ni10 alloy samples sintered at 950°C achieved near-full densification, while the Zr90Ti5Ni5 alloy sample had a relative density of only 81.7%, with numerous pore defects remaining in the cross-section. This indicates that as the Zr content increases, the overall melting point of the alloy rises. XRD and SEM analysis results show that the ZrTiNi alloys consist mainly of Zr(Ti) solid solution as the primary phase and Ni-Zr(Ti) intermetallic compounds. Additionally, increasing Zr content promotes the formation of Zr-rich solid solution phases, which inhibits the formation of intermetallic compounds to some extent. Quasi-static compression tests reveal that the densified Zr70Ti15Ni15 and Zr80Ti10Ni10 alloy samples both have compressive strengths exceeding 1200MPa, providing a solid foundation for blast loading resistance and armor-piercing penetration. In ballistic gun tests, the Zr80Ti10Ni10 alloy projectile successfully penetrated the front steel plate at a velocity of 1029m/s and sustained the ignition of jet fuel, demonstrating excellent impact-induced ignition properties.

    参考文献
    相似文献
    引证文献
引用本文

伍泽宸,赵孔勋,刘桂涛,刘凯,段炼,杨洪泰,刘奕彤,梁栋.低温热熔ZrTiNi含能材料组织性能研究[J].稀有金属材料与工程,,().[Zechen Wu, Kongxun Zhao, Liu Guitao, Kai Liu, Lian Duan, Hongtai Yang, Yitong Liu, Dong Liang. Microstructure and properties of low-temperature hot-melt ZrTiNi energetic materials[J]. Rare Metal Materials and Engineering,,().]
DOI:[doi]

复制
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2025-01-09
  • 最后修改日期:2025-03-04
  • 录用日期:2025-03-06
  • 在线发布日期:
  • 出版日期: