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固溶处理Mg-0.5Zr-1.8Zn-xGd生物可降解镁合金的微观组织、力学性能和腐蚀性能
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1.河南科技大学 材料科学与工程学院,河南 洛阳 471023;2.有色金属共性技术河南省协同创新中心,河南 洛阳 471023;3.洛阳船舶材料研究所,河南 洛阳 471000

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Microstructures, Mechanical Properties and Corrosion Behavior of Solution-Treated Mg-0.5Zr-1.8Zn-xGd Biodegra-dable Alloys
Author:
Affiliation:

1.School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, China;2.Collaborative Innovation Center of Nonferrous Metals of Henan Province, Luoyang 471023, China;3.Luoyang Ship Material Research Institute, Luoyang 471000, China

Fund Project:

Education Department of Henan Province (20A430010); National Natural Science Foundation of China (U1804146)

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    摘要:

    研究了Mg-0.5Zr-1.8Zn-xGd (x=0,0.5,1.0,1.5,2.0,2.5,质量分数,%) 镁合金经过470 ℃和10 h固溶处理后的组织、力学性能和耐腐蚀性能。结果表明,Gd含量在0%~2.5%范围内,随着Gd含量增加,合金晶粒尺寸逐渐减小。当Gd含量低于1.5%时,合金元素几乎完全固溶于合金基体中,第二相主要由纳米尺度的(Mg,Zn)3Gd析出颗粒组成。当Gd含量在1.5%~2.5%范围时,合金中出现未固溶的微米尺度的(Mg,Zn)3Gd相,并且该相数量和尺寸随着Gd含量增加而增加。由于组织均匀分布和纳米尺寸的第二相颗粒存在,Mg-0.5Zr-1.8Zn-1.5Gd合金具有优异的力学性能和耐腐蚀性能。在120 h浸泡实验中,Mg-0.5Zr-1.8Zn-1.5Gd合金平均腐蚀速率首先降低,然后增加,接着缓慢降低,最后,随着浸泡时间延长,腐蚀速率最终变得稳定。

    Abstract:

    The microstructure, mechanical and anticorrosion properties of Mg-0.5Zr-1.8Zn-xGd (x=0, 0.5, 1.0, 1.5, 2.0, 2.5, wt%) alloys were investigated after a solution treatment at 470 ℃ for 10 h. Results indicate that the grain size of the alloy decreases with increasing the Gd content in the range of 0wt%~2.5wt%. When the Gd content is less than 1.5wt%, the alloy elements are more completely dissolved into the alloy matrix, and the second phase is mainly composed of nanoscale (Mg, Zn)3Gd precipitated particle. At the range of 1.5wt%~2.5wt%, the insoluble micron-scale (Mg, Zn)3Gd phase emerges in the alloy, and the number and size of the (Mg, Zn)3Gd phase increase with the Gd content. The Mg-0.5Zr-1.8Zn-1.5Gd alloy shows excellent mechanical properties and anticorrosive ability, which can be attributed to a more homogeneous microstructure and the presence of nanometric secondary phase particles. In the 120 h immersion experiment, the average corrosion rate of the Mg-0.5Zr-1.8Zn-1.5Gd alloy deceases at first, then increases, and then decreases slowly. At last, with the increase of immersion time, it eventually becomes stable.

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姚怀,熊毅,查小琴,李欢,师慧娜,刘亚.固溶处理Mg-0.5Zr-1.8Zn-xGd生物可降解镁合金的微观组织、力学性能和腐蚀性能[J].稀有金属材料与工程,2021,50(6):1919~1927.[Yao Huai, Xiong Yi, Zha Xiaoqin, Li Huan, Shi Huina, Liu Ya. Microstructures, Mechanical Properties and Corrosion Behavior of Solution-Treated Mg-0.5Zr-1.8Zn-xGd Biodegra-dable Alloys[J]. Rare Metal Materials and Engineering,2021,50(6):1919~1927.]
DOI:10.12442/j. issn.1002-185X. E20200019

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历史
  • 收稿日期:2020-05-27
  • 最后修改日期:2020-06-09
  • 录用日期:2020-06-10
  • 在线发布日期: 2021-07-07
  • 出版日期: 2021-06-30