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Mo添加对Al19Fe20- x Co20- x Ni41Mo2 x 共晶高熵合金摩擦学性能的影响
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国家自然科学基金项目(面上项目,重点项目,重大项目)


Effect of Mo Addition on Tribological Properties of Al19Fe20- x- Co20- x Ni41Mo2 x Eutectic High-Entropy Alloys
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National Natural Science Foundation of China (52271147, 12261160364, 52371154); Guangdong Basic and Applied Basic Research Foundation (2023A1515012158)

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    摘要:

    研究了Al19Fe20-xCo20-xNi41Mo2xx=0,1,2,3,4,5)共晶高熵合金(EHEAs)的摩擦学性能。结果表明,添加微量Mo的EHEA可形成面心立方(fcc)+B2共晶组织,而添加相对较高含量Mo的EHEAs可形成fcc+B2+μ树枝状组织。Mo元素有利于提高L12相的强度和B2相的延性。然而,随着Mo含量的增加,生成的富Mo μ相降低了EHEAs的强度和塑性。Al19Fe18Co18Ni41Mo4 EHEA具有高强度和高延展性的最佳组合。增加Mo含量可以提高EHEAs的抗氧化性。随着Mo含量的增加,EHEA在滑动过程中形成了抗氧化性增强的摩擦氧化物层,摩擦系数单调下降。本研究为Al19Fe20-xCo20-xNi41Mo2x EHEAs的摩擦学性能研究提供了指导。

    Abstract:

    Tribological properties of Al19Fe20-xCo20-xNi41Mo2x (x=0, 1, 2, 3, 4, 5) eutectic high-entropy alloys (EHEAs) were investigated in this research. Results show that EHEAs with trace Mo addition can form the face-centered cubic (fcc)+B2 eutectic microstructure, whereas EHEAs with relatively higher Mo content can form fcc+B2+μ dendritic microstructure. Mo element is beneficial to the strength enhancement of L12 phase and the ductility improvement of B2 phase. However, with increasing the Mo content to x>2, the resultant Mo-rich μ phase degrades the strength and plasticity of EHEAs. Al19Fe18Co18Ni41Mo4 EHEA has the optimal combination of high strength and high ductility. Increasing Mo content can improve the oxidation resistance of EHEAs. With increasing the Mo content, EHEA forms a tribo-oxide layer with improved oxidation resistance during sliding process, and the friction coefficient is monotonically decreased. This research provides guidance for the investigation of tribological properties of Al19Fe20-xCo20-xNi41Mo2x EHEAs.

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彭振,郭庆宇,孙健,李可然,栾亨伟,龚攀.Mo添加对Al19Fe20- x Co20- x Ni41Mo2 x 共晶高熵合金摩擦学性能的影响[J].稀有金属材料与工程,2024,53(1):17~22.[Peng Zhen, Guo Qingyu, Sun Jian, Li Keran, Luan Hengwei, Gong Pan. Effect of Mo Addition on Tribological Properties of Al19Fe20- x- Co20- x Ni41Mo2 x Eutectic High-Entropy Alloys[J]. Rare Metal Materials and Engineering,2024,53(1):17~22.]
DOI:10.12442/j. issn.1002-185X. E20230033

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历史
  • 收稿日期:2023-09-12
  • 最后修改日期:2023-10-24
  • 录用日期:2023-11-13
  • 在线发布日期: 2024-01-25
  • 出版日期: 2024-01-24