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石墨抗氧化SiC涂层的制备与性能研究
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东北大学,东北大学,东北大学,东北大学,东北大学

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国家自然科学基金资助(项目号51272039),中央高校基本科研业务费资助(项目号N130810003,N150203001)


Preparation and oxidation behavior of SiC coating for graphite materials
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Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education ATM,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education ATM,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education ATM,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education ATM,Northeastern University,Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education ATM,Northeastern University

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    摘要:

    本文以SiC、Si和酚醛树脂为主要原料,通过浸涂和气相渗硅两步法在石墨表面制备了SiC抗氧化涂层。利用XRD、SEM研究了涂层的相组成与形貌。结果表明,气相渗硅后涂层的主相为α-SiC,β-SiC和Si,其中Si是气相渗硅过程中残留的。涂层与基体之间具有过渡结构,致密度良好。抗氧化和抗热震实验表明:由气相渗硅工艺制备的SiC涂层结构致密,具有良好的抗氧化性能,1200℃空气条件下氧化16 h后试样每小时增重量约为2.18 mg/cm2。涂层具有良好的抗热震性能,经1000 ℃—室温循环热震15次后试样质量变化百分率仅为-0.17%。

    Abstract:

    SiC coating for protecting graphite materials against oxidation was prepared using SiC, Si and thermosetting phenolic resin as materials by vapor silicon infiltration process(VSI). SEM and XRD showed that a dense SiC coating was obtained with a C/SiC gradient inner layer acting as bonding layer and combined well with the outlayer SiC coating , the main phases of coating consisted of α-SiC, β-SiC and Si, and free Si was residual after the VSI process. The as-obtained SiC coating can effectively protect graphite after oxidation for 16 h at 1200 ℃ with a weight gain about 2.18 mg/cm2 in air and endured the thermal shock between 1000℃ and room temperature for 15 cycles with only 0.17wt% weight loss.

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姜岩,叶超超,茹红强,岳新艳,王伟.石墨抗氧化SiC涂层的制备与性能研究[J].稀有金属材料与工程,2018,47(S1):294~297.[Jiang Yan, Ye Chaochao, Ru Hongqiang, Yue Xinyan, Wang Wei. Preparation and oxidation behavior of SiC coating for graphite materials[J]. Rare Metal Materials and Engineering,2018,47(S1):294~297.]
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  • 收稿日期:2017-07-03
  • 最后修改日期:2017-07-03
  • 录用日期:2018-01-29
  • 在线发布日期: 2018-10-22
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