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纳米SiC对BN-ZrO2-SiC复相陶瓷结构与力学性能的影响
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红河学院理学院,红河学院理学院,红河学院理学院,清华大学新型陶瓷与精细工艺国家重点实验室,红河学院理学院

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国家自然科学基金(项目号51762015、51362011和51562009)和红河学院中青年学术骨干培养项目(项目号2016GG0306)


Effect of Nano SiC on Microstructure and Mechanical Properties of BN-ZrO2-SiC Multiphase Ceramics
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College of Science,Honghe University,College of Science,Honghe University,College of Science,Honghe University,State Key Laboratory of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,College of Science,Honghe University

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    摘要:

    以h-BN、ZrO2、SiC粉体为原料,添加8%的A2O3-Y2O3为烧结助剂,采用放电等离子烧结技术快速制备了h-BN-ZrO2-SiC复相陶瓷,研究了纳米SiC颗粒添加量对h-BN-ZrO2-SiC复相陶瓷的致密化、显微结构及力学性能的影响。结果表明:纳米SiC颗粒能有效促进h-BN-ZrO2-SiC复相陶瓷的烧结,提高烧结样品的致密度和力学性能,而且随着SiC添加量的增大,烧结样品的抗弯强度、断裂韧性和弹性模量均呈增加的趋势,特别是弹性模量的增加趋势比较明显。在纳米SiC添加量为25%时获得较佳的力学性能,此时抗弯强度、断裂韧性和弹性模量分别为268.4MPa、3.24MPa.m1/2和115GPa。其原因主要是由于纳米SiC颗粒能较好的起到空隙填充、弥散强化及晶界钉扎作用,有利于提高相间的结合强度,减少相间由于热失配产生的残余应力。这样裂纹在扩展时将会消耗更多的断裂能,提高复相陶瓷的抗弯强度和断裂韧性。

    Abstract:

    h-BN-ZrO2-SiC multiphase ceramics were prepared rapidly by spark plasma sintering (SPS) with h-BN, ZrO2 and SiC powders as raw materials and 8%(Al2O3+Y2O3) as sintering aids. The effects of nano SiC content on the densification, microstructure and mechanical properties of h-BN-ZrO2-SiC multiphase ceramics were systematically investigated. The results show that the addition of nano SiC particles can effectively promote the sintering and increase density and mechanical properties of the sintered samples at a low sintering temperature. The flexural strength, fracture toughness and elastic modulus all increase with the content increase of nano SiC, especially, the increasement of the elastic modulus is obvious. The comparison of all results shows that the sample with the SiC content of 25% has optimal mechanical properties than other samples, and the flexural strength, fracture toughness and elastic modulus are 268.4 MPa, 3.24 MPa.m1/2 and 115 GPa, respectively. The reason is mainly due to the nano SiC particles can better play a gap filling, dispersion strengthening and grain boundary pinning effect than ZrO2, which are beneficial to improve the bonding strength between the phases and reduce the residual stress due to thermal mismatch. As a result, the more fracture energy was absorbed during the crack propagation process, and the flexural strength and fracture toughness increased.

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翟凤瑞,单科,卢敏,谢志鹏,易中周.纳米SiC对BN-ZrO2-SiC复相陶瓷结构与力学性能的影响[J].稀有金属材料与工程,2018,47(S1):393~397.[Fengrui Zhai, Ke Shan, Lu Min, Zhipeng Xie, Zhongzhou Yi. Effect of Nano SiC on Microstructure and Mechanical Properties of BN-ZrO2-SiC Multiphase Ceramics[J]. Rare Metal Materials and Engineering,2018,47(S1):393~397.]
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  • 收稿日期:2017-07-13
  • 最后修改日期:2018-02-01
  • 录用日期:2018-02-01
  • 在线发布日期: 2018-10-22
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