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烧结工艺对W-Ni-Fe合金组织和力学性能的影响
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作者单位:

1.天津大学材料科学与工程学院;2.安泰天龙钨钼科技有限公司;3.海天塑机集团有限公司

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基金项目:

the National Key R&D Program of China (2023YFB12002), National Natural Science Foundation of China (Grant No. U22A20172 and 52171044)


Study on microstructure and properties of 93W-4.6Ni-2.4Fe prepared by ball-milling and liquid phase sintering
Author:
Affiliation:

1.School of Materials Science and Engineering,Tianjin University;2.ATTL Advanced Materials Co,Ltd Beijing;3.Haitian Plastics Machinery Group Co,Ltd Ningbo

Fund Project:

the National Key R&D Program of China (2023YFB12002), National Natural Science Foundation of China (Grant No. U22A20172 and 52171044)

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    摘要:

    为了制备出优异、经济友好的钨重合金,在1450-1510°C的烧结温度范围内,通过球磨(BM)和液相烧结(LPS)制备了93W-4.6Ni-2.4Fe(wt.%)合金。进一步研究了试样的微观结构和断裂模式。在不同烧结温度下,烧结的试样表现出相似的两相显微结构和韧性断裂模式。随着烧结温度的升高,钨颗粒尺寸也逐渐增大。当烧结温度达到或超过1480°C时,合金相对密度达到99.0%以上。确定1480°C为具有最佳抗拉强度(940 MPa)和延伸率(32.6%)组合的试样的烧结温度。在1480°C下烧结的试样具有优异的延展性,这与γ相的网络结构、韧窝的均匀分布以及两相的协同作用有关。试样的高强度归因于细化的钨颗粒尺寸和球形的钨颗粒。

    Abstract:

    In order to produce economical tungsten alloys with superior mechanical properties, 93W-4.6Ni-2.4Fe (wt.%) tungsten heavy alloys were fabricated by ball milling (BM) and liquid phase sintering (LPS) at a temperature range of 1450-1510°C. The microstructure and the fracture modes of the specimens were further examined. The specimens sintered at different temperatures display similar dul-phase microstructure and ductile fracture modes. With the increase of the sintering temperature, the tungsten particle size also gradually grows. At and above the temperature of 1480°C, the relative density reaches above 99.0%. The optimal sintering temperature of the specimen with the best tensile strength (940 MPa) and elongation (32.6%) combination is determined to be 1480°C. The excellent ductility of the specimen sintered at 1480°C is associated with the network structure of γ phase, the uniform distribution of dimples and the synergistic effect of these two phases. The high strength of the specimen is attributed to the refined tungsten particle size and the spherical tungsten particles.

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王姿曈,董帝,熊宁,徐嘉伟,董智,马宗青.烧结工艺对W-Ni-Fe合金组织和力学性能的影响[J].稀有金属材料与工程,,().[Zitong Wang, Di Dong, Ning Xiong, Jiawei Xu, Zhi Dong, Zongqing Ma. Study on microstructure and properties of 93W-4.6Ni-2.4Fe prepared by ball-milling and liquid phase sintering[J]. Rare Metal Materials and Engineering,,().]
DOI:10.12442/j. issn.1002-185X.20230778

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  • 收稿日期:2023-12-01
  • 最后修改日期:2024-02-19
  • 录用日期:2024-02-26
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