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温度对Pt-Al涂层第三代低成本单晶高温合金蠕变行为的影响
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1.沈阳工业大学材料科学与工程学院;2.中国科学院金属研究所

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国家重点基础研究发展计划(973计划),中国博士后科学基金,辽宁省优秀青年基金,燃气轮机工程科学中心


Influence of temperatures on the creep behaviour of a third-generation low cost single crystal superalloy applied with Pt-Al coating
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National Key Research and Development Program of China, China Postdoctoral Science Foundation , Excellent Youth Foundation of Liaoning Province, and Science Center for Gas Turbine Project

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    摘要:

    评估了应用温度对含铂铝涂层的第三代低成本单晶(SX)高温合金蠕变行为的影响。在1100℃/137MPa、1120℃/137MPa和1140℃/137MPa条件下观察蠕变损伤。在所有测试条件中,裸基体高温合金均优于带涂层高温合金。在 1100℃/137 MPa下进行测试时,蠕变寿命最明显地缩短了50%。在更高温度下(1120℃和1140℃),铂铝涂层向单晶高温合金基体的裂纹扩展速度减慢,从而减少了机械性能的下降,涂层裂纹尖端的氧化和铝扩散到涂层裂纹中形成氧化物,而不是渗透到单晶基体中,导致涂层下基体的微结构退化缓慢。然而,在1100℃时,涂层/单晶合计基底的微观结构由于铝的内部扩散而退化。这种扩散机制在 1100℃左右形成了有害的TCP相。TEM结果显示,在1120℃和1140℃时,涂层下的单晶合金基底的位错与内部高温合金的位错相比保持相对不变。与此相反,涂层下基底的位错网络变得稀疏,在1100℃时切割成相的超位错数量增加。

    Abstract:

    The influence of applied temperatures has been evaluated on the creep rupture life of a third-generation low-cost single crystal (SX) superalloy with Pt-Al coating. The damage was observed at 1100°C, 1120°C, and 1140°C under the applied stress of 137 MPa. The bare high-temperature alloy outperforms the superalloy with coating in all test parameters. The most significant reduction in creep life up to 50 % occurs when tested at 1100°C/137 MPa. Increasing the temperature from 1100°C to 1140°C improved Creep life of coated superalloys and minimized the reduction to 20% as compared to the bare superalloy. At higher temperatures (1120°C and 1140°C), sluggish crack propagation in Pt-Al coatings to SX superalloy substrate, reducing mechanical property degradation. Oxidation of coating crack tips and Al diffusion into coating cracks to form oxides, rather than penetration into the SX substrate, cause microstructures in the substrate beneath the layer to degrade slowly. At 1100°C, however, the coating/SX substrate microstructure degraded due to the Al internal diffusion. This diffusion mechanism governs the formation of harmful TCP phases at around 1100°C. Therefore, the microstructure stability of coated alloys at 1120°C and 1140°C is better than that at 1100°C. The TEM results revealed that at 1120°C and 1140°C, the dislocation of the SX substrate beneath the coating remained relatively unchanged compared to that in the inner superalloy. In contrast, the dislocation network of the substrate beneath the coating became sparse, and the number of superdislocations cutting into ?? phases increased at 1100°C. This change further intensified the mechanical property degradation of the coat on the SX superalloy. This study aims to provide guidance on appropriate service conditions for high-temperature protective coatings, enabling the development of more advanced coatings.

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张舸,陶稀鹏,S. M. Abbas Jafri,王新广,张松,张春华,梁静静,李金国,孙晓峰,周亦胄.温度对Pt-Al涂层第三代低成本单晶高温合金蠕变行为的影响[J].稀有金属材料与工程,,().[Zhang Ge, Tao Xipeng, S. M. Abbas Jafri, Wang Xinguang, Zhang Song, Zhang Chunhua, Liang Jingjing, Li Jinguo, Sun Xiaofeng, Zhou Yizhou. Influence of temperatures on the creep behaviour of a third-generation low cost single crystal superalloy applied with Pt-Al coating[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-01-08
  • 最后修改日期:2024-03-20
  • 录用日期:2024-03-22
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