周键,贾昱,宋小三.Ti/IrO2+MnO2电极在酸性溶液中的析氧反应动力学研究[J].稀有金属材料与工程,2023,52(4):1287~1295.[Zhou Jian,Jia yu,Song xiaosan.Kinetics of oxygen evolution reaction on Ti/IrO2+MnO2 electrodeform acid solution[J].Rare Metal Materials and Engineering,2023,52(4):1287~1295.]
[doi]
Ti/IrO2+MnO2电极在酸性溶液中的析氧反应动力学研究
投稿时间:2022-03-13  修订日期:2022-05-09
中文关键词:  Ti/IrO2+MnO2电极  析氧反应动力学  Tafel曲线
基金项目:国家自然科学基金资助(51804150),甘肃省科技计划资助(20JR2RA002),甘肃省黄河水环境重点实验室开放基金资助(21YRWEK002)
中文摘要:
      采用涂覆热分解法制备Ti/IrO2+MnO2复合电极,利用慢速线性电位扫描伏安法测试Ti/IrO2+MnO2电极的准稳态极化曲线并深入地研究析氧反应动力学,得到了相关动力学参数、反应历程及速度控制步骤。通过分析经欧姆电压降修正的Tafel曲线,较好地解释了Tafel直线区域的双斜率现象,基于此提出析氧反应动力学方程并进行数学推导,较好地符合实验结果。实验所得氢离子反应级数约为零,低电位区与高电位区的表观活化能分别为30.31kJ/mol和13.64kJ/mol,进一步证明该数学模型的正确性。
Kinetics of oxygen evolution reaction on Ti/IrO2+MnO2 electrodeform acid solution
英文关键词:Ti/IrO2+MnO2 electrode  Kinetics of oxygen evolution reaction  Tafel curve
英文摘要:
      Ti/IrO2+MnO2 composite electrodes were prepared by thermal decomposition. The kinetics of oxygen evolution reaction on Ti/IrO2+ MnO2 electrodes were studied deeply with quasi-stationary polarization curve recorded by slow linear potential sweep voltammetry. The related kinetics parameters, reaction process and rate determining steps were obtained. Tafel linear regions wih double slopes were explained well by analyzing the ohmic voltage drop corrected Tafel curves. Kinetics equations based on the proposed oxygen evolution reaction mechanism were deduced mathematically, which were in good agreement with the experimental results. The reaction order of hydrogen ion close to 0, the one of apparent activation energy of 30.31kJ/mol in the low potential region and the other of 13.64kJ/mol in the high potential region, further proved the correctness of above mathematical model.
作者单位E-mail
周键* 兰州交通大学 luck849200@126.com 
贾昱兰州交通大学  
宋小三兰州交通大学  
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